Alemayehu Abraham B, Vazquez-Lima Hugo, McCormick Laura J, Ghosh Abhik
Department of Chemistry and Center for Theoretical and Computational Chemistry, UiT - The Arctic University of Norway, 9037 Tromsø, Norway.
Chem Commun (Camb). 2017 May 30;53(43):5830-5833. doi: 10.1039/c7cc01549f.
The homoleptic sandwich compounds - Mo and W biscorroles - have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.
同配夹心化合物——钼和钨双咕啉——为相对论效应的实验研究提供了一个新平台。还原电位200 mV的差异以及近红外光谱特征显著的130 nm位移已被确认为相对论效应在这些配合物性质上的表现。
