State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences , No. 3888 Dongnanhu Road, Changchun 130033, People's Republic of China.
University of the Chinese Academy of Sciences , Beijing 100049, People's Republic of China.
ACS Appl Mater Interfaces. 2017 May 31;9(21):18248-18253. doi: 10.1021/acsami.7b01067. Epub 2017 May 18.
Carbon dot (CD)-NaCl hybrid crystals are obtained by incorporating the CDs into NaCl matrix through a simple process. The embedded CDs have added the luminescence centers into NaCl, and as a result, the hybrid crystals present the fluorescence centered at 510 nm under the illumination of 365 nm light. Meanwhile, the phosphorescence with an average lifetime of 314 ms is achieved after the 365 nm light was turned off. Furthermore, optical gain and lasing phenomenon has been observed from hybrid crystals. When the pump power is low, a weak spontaneous emission can be observed from the hybrid crystal, whereas the lasing action was observed under high pump power. The lasing threshold is found to be 0.08 mW and corresponding Q factor is calculated to be 447. The tiny cubic crystal in hybrid crystals offers the whispering gallery mode (WGM) resonant cavity for lasing emission. That has provided a new approach for realizing lasing materials.
碳点(CD)-NaCl 混合晶体是通过简单的过程将 CDs 掺入 NaCl 基质中获得的。嵌入的 CDs 为 NaCl 添加了发光中心,因此,在 365nm 光的照射下,混合晶体在 510nm 处呈现荧光。同时,在关闭 365nm 光后,实现了平均寿命为 314ms 的磷光。此外,从混合晶体中观察到了光学增益和激光现象。当泵浦功率较低时,可以从混合晶体中观察到较弱的自发发射,而在高泵浦功率下观察到了激光作用。发现激光阈值为 0.08mW,相应的 Q 因子计算为 447。混合晶体中的微小立方晶体为激光发射提供了 whispering gallery 模式(WGM)共振腔。这为实现激光材料提供了一种新方法。