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采用新型过热蒸汽法从碳纤维增强环氧树脂基复合材料中回收和表征碳纤维。

Recycling and characterization of carbon fibers from carbon fiber reinforced epoxy matrix composites by a novel super-heated-steam method.

机构信息

R&D Division, Korea Institute of Carbon Convergence Technology, Jeonju 54853, South Korea; Department of Organic Materials and Fiber Engineering, Chonbuk National University, Jeonju 54896, South Korea.

R&D Division, Korea Institute of Carbon Convergence Technology, Jeonju 54853, South Korea.

出版信息

J Environ Manage. 2017 Dec 1;203(Pt 3):872-879. doi: 10.1016/j.jenvman.2017.05.015. Epub 2017 May 12.

DOI:10.1016/j.jenvman.2017.05.015
PMID:28506669
Abstract

In order to manufacture high quality recycled carbon fibers (R-CFs), carbon fiber-reinforced composite wastes were pyrolysed with super-heated steam at 550 °C in a fixed bed reactor for varying reaction times. The mechanical and surface properties of the R-CFs were characterized with a single fiber tensile test, interface shear strength (IFSS), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The surface analysis showed that there was no matrix char residue on the fiber surfaces. The tensile strength and IFSS values of the R-CFs were 90% and 115% compared to those of virgin carbon fibers (V-CFs), respectively. The recycling efficiency of the R-CFs from the composites were strongly dependent on the pyrolysis temperature, reaction time, and super-heated steam feeding rate.

摘要

为了制造高质量的回收碳纤维(R-CFs),将碳纤维增强复合材料废物在固定床反应器中用过热蒸汽在 550°C 下进行热解,反应时间不同。通过单纤维拉伸试验、界面剪切强度(IFSS)、扫描电子显微镜(SEM)和 X 射线光电子能谱(XPS)对 R-CFs 的机械和表面性能进行了表征。表面分析表明,纤维表面没有基质炭残留物。与原始碳纤维(V-CFs)相比,R-CFs 的拉伸强度和 IFSS 值分别提高了 90%和 115%。复合材料中 R-CFs 的回收效率强烈依赖于热解温度、反应时间和过热蒸汽进料速率。

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