基于乙烯基七富烯的太阳能热电池能量释放的有效触发因素。
An effective trigger for energy release of vinylheptafulvene-based solar heat batteries.
作者信息
Cacciarini Martina, Vlasceanu Alexandru, Jevric Martyn, Nielsen Mogens Brøndsted
机构信息
Department of Chemistry 'Ugo Schiff', Università di Firenze, Via della Lastruccia, 3-13, I-50019 Sesto Fiorentino, Italy.
出版信息
Chem Commun (Camb). 2017 May 30;53(43):5874-5877. doi: 10.1039/c7cc01050h.
PMID:28508907
Abstract
Stoichiometric copper(i) tetrakis(acetonitrile) is found to activate the thermal ring-closure reaction of a series of high-energy vinylheptafulvene isomers to the corresponding low-energy and photoactive dihydroazulenes, allowing the release of energy upon request.
摘要
化学计量的四（乙腈）合铜（I）被发现可激活一系列高能乙烯基庚富烯异构体的热闭环反应，生成相应的低能且具有光活性的二氢薁，从而能够按需释放能量。
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