Cacciarini Martina, Vlasceanu Alexandru, Jevric Martyn, Nielsen Mogens Brøndsted
Department of Chemistry 'Ugo Schiff', Università di Firenze, Via della Lastruccia, 3-13, I-50019 Sesto Fiorentino, Italy.
Chem Commun (Camb). 2017 May 30;53(43):5874-5877. doi: 10.1039/c7cc01050h.
Stoichiometric copper(i) tetrakis(acetonitrile) is found to activate the thermal ring-closure reaction of a series of high-energy vinylheptafulvene isomers to the corresponding low-energy and photoactive dihydroazulenes, allowing the release of energy upon request.
化学计量的四（乙腈）合铜（I）被发现可激活一系列高能乙烯基庚富烯异构体的热闭环反应，生成相应的低能且具有光活性的二氢薁，从而能够按需释放能量。
