Flocculation and Dewatering of Mature Fine Tailings Using Temperature-Responsive Cationic Polymers.

Temperature-responsive copolymer with cationic charge was prepared with N-isopropylacrylamide (NIPAm) and 2-aminoethyl methacrylamide hydrochloride (AEMA) by conventional free-radical polymerization. The flocculation performance of the copolymer, poly(AEMA-st-NIPAm), was compared to five different mixture ratios of polyNIPAm and cationic poly(acrylamide-st-diallyldimethylammonium chloride) (poly(AAm-st-DADMAC)). The effects of polymer mixture ratios, polymer dosages, and temperature on solid-liquid separation as a function of initial settling rates (ISR), supernatant turbidity, sediment solid content, and water recovery were investigated. Poly(NIPAm) can facilitate particles aggregation by bridging and hydrogen bonding under lower critical solution temperature (LCST); whereas, at temperature above LCST, the adsorption of poly(NIPAm) chains on particles can be enhanced by hydrophobic interaction. A two-step (25 °C → 50 °C → 25 °C) consolidation can further enhance the sediment solid content by polyNIPAm. While the neutral property of polyNIPAm resulted in high turbidity of supernatant, mixing with poly(AAm-st-DADMAC) increases the clarity of supernatant by neutralization of fine particles. The copolymer poly(AEMA-st-NIPAm) functions as a polyelectrolyte to enhance the polymer adsorption onto particles via electrostatic interactions, thus further improving ISR and supernatant clarity.