Department of Molecules & Materials, MESA+ Institute, University of Twente, 7500 AE Enschede, The Netherlands.
Membrane Materials and Processes, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.
Langmuir. 2024 Mar 5;40(9):4545-4566. doi: 10.1021/acs.langmuir.3c03439. Epub 2024 Feb 22.
Biomaterials often contain large quantities of water (50-98%), and with the current transition to a more biobased economy, drying these materials will become increasingly important. Contrary to the standard, thermodynamically inefficient chemical and thermal drying methods, dewatering by membrane separation will provide a sustainable and efficient alternative. However, biomaterials can easily foul membrane surfaces, which is detrimental to the performance of current membrane separations. Improving the antifouling properties of such membranes is a key challenge. Other recent research has been dedicated to enhancing the permeate flux and selectivity. In this review, we present a comprehensive overview of the design requirements for and recent advances in dewatering of biomaterials using membranes. These recent developments offer a viable solution to the challenges of fouling and suboptimal performances. We focus on two emerging development strategies, which are the use of electric-field-assisted dewatering and surface functionalizations, in particular with hydrogels. Our overview concludes with a critical mention of the remaining challenges and possible research directions within these subfields.
生物材料通常含有大量的水(50-98%),随着当前向更基于生物的经济的转变,干燥这些材料将变得越来越重要。与标准的、热力学效率低下的化学和热干燥方法相反,通过膜分离脱水将提供一种可持续和高效的替代方法。然而,生物材料很容易污染膜表面,这对当前膜分离的性能不利。提高此类膜的抗污染性能是一个关键挑战。其他最近的研究致力于提高渗透通量和选择性。在这篇综述中,我们全面介绍了使用膜对生物材料进行脱水的设计要求和最新进展。这些最新进展为解决污染和性能不佳的挑战提供了可行的解决方案。我们重点介绍了两种新兴的发展策略,即使用电场辅助脱水和表面功能化,特别是水凝胶。我们的综述最后还提到了这些子领域中仍然存在的挑战和可能的研究方向。