Mandal A K, Sinha O P
Department of Metallurgical Engineering, IIT (BHU), Varanasi, India.
Waste Manag Res. 2017 Aug;35(8):810-819. doi: 10.1177/0734242X17707575. Epub 2017 May 24.
The issues of disposal and environmental problems are increased by the generation of bottom ash from the thermal power plants day by day; hence, its recycling is required. The present study aimed to make thermal insulation blocks using as raw material bottom ash and iron ore slime as a binder and to characterize their engineering properties. Two different fineness values of bottom ash were considered with varying amounts of iron ore slime (0-10%) to make the blocks. Blocks were dried followed by firing at 1000, 1100 and 1200°C, respectively. Cold crushing strength, density and thermal conductivity of these fired blocks showed increasing behaviour with firing temperature, fineness of bottom ash and iron ore slime content. In contrast, a reverse trend was observed in the case of porosity. With increasing firing temperature, the formation of lower melting phases like iron silicate followed by iron aluminium silicate was observed, which imparts the strength inside the blocks. The coarser particles of bottom ash increase the interparticle spaces, which enhances the apparent porosity, resulting in higher thermal insulation property in the blocks. Blocks having better thermal insulation property could be possible to make effectively from coarse bottom ash by adding iron ore slime as a binder.
火力发电厂产生的底灰日益增加了处置问题和环境问题,因此需要对其进行回收利用。本研究旨在以底灰为原料、以铁矿泥为粘结剂制作保温砌块,并对其工程性能进行表征。考虑了两种不同细度的底灰,并加入不同量的铁矿泥(0 - 10%)来制作砌块。砌块先进行干燥,然后分别在1000℃、1100℃和1200℃下烧制。这些烧制砌块的冷压强度、密度和热导率随烧制温度、底灰细度和铁矿泥含量的增加而呈现上升趋势。相比之下,孔隙率则呈现相反的趋势。随着烧制温度的升高,观察到有低熔点相如硅酸铁以及随后的铁铝硅酸盐形成,这赋予了砌块内部强度。底灰的粗颗粒增加了颗粒间的空隙,从而提高了表观孔隙率,使砌块具有更高的保温性能。通过添加铁矿泥作为粘结剂,有可能有效地利用粗底灰制作出具有更好保温性能的砌块。