铜（I）介导的芳基重氮盐对乙烯基叠氮化物的碳胺化反应：N-取代-1,2,3-三唑的合成
Copper(i)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N-substituted 1,2,3-triazoles.
作者信息
Liu Zhenhua, Ji Huimin, Gao Wen, Zhu Guangyu, Tong Lili, Lei Fengcai, Tang Bo
机构信息
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Institute of Biomedical Sciences, Shandong Normal University, Jinan 250014, P. R. China.
出版信息
Chem Commun (Camb). 2017 Jun 6;53(46):6259-6262. doi: 10.1039/c7cc02391j.
A copper(i)-mediated carboamination cascade reaction between vinyl azides and aryldiazonium salts is described. Functionally diverse N-substituted 1,2,3-triazoles were obtained in moderate to good yields through novel difunctionalization of vinyl azides by aryldiazonium salt sources. This method has a wide scope, good functional-group tolerance and insensitivity to an ambient atmosphere.
描述了一种铜（I）介导的乙烯基叠氮化物与芳基重氮盐之间的碳胺化串联反应。通过芳基重氮盐源对乙烯基叠氮化物进行新型双官能化反应，以中等至良好的产率获得了功能多样的N-取代1,2,3-三唑。该方法具有广泛的适用范围、良好的官能团耐受性以及对环境气氛不敏感的特点。
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