用于合成α-偶氮苯酚的芳基重氮盐的一锅双官能化反应
One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of -Azophenols.
作者信息
Liu Zhenhua, Fang Yang, Liu Yi, Fu Wei, Gan Xingxing, Gao Wen, Tang Bo
机构信息
Key Laboratory of Molecular and Nano Probes, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Ministry of Education, Shandong Normal University, Jinan, China.
Department of Pharmacy, Zibo Central Hospital, Zibo, China.
出版信息
Front Chem. 2022 Jan 26;10:818627. doi: 10.3389/fchem.2022.818627. eCollection 2022.
A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric -azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy to facilitate the synthesis of -azophenols.
实现了一种新型的芳基重氮盐双官能团化反应，可一步生成对称和不对称的偶氮苯酚。该方法通过在温和的反应条件下依次进行区域选择性的芳基C-O和C-N键构建来进行，开启了一种促进偶氮苯酚合成的新反应策略。
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