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有机合成中的乙烯基叠氮化物:综述

Vinyl azides in organic synthesis: an overview.

作者信息

Gholami Fateme, Yousefnejad Faeze, Larijani Bagher, Mahdavi Mohammad

机构信息

School of Chemistry, College of Science, University of Tehran Tehran Iran.

Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences Tehran Iran

出版信息

RSC Adv. 2023 Jan 4;13(2):990-1018. doi: 10.1039/d2ra06726a. eCollection 2023 Jan 3.

Abstract

Among organic azides, vinyl azides have attracted significant attention, because of their unique properties in organic synthesis, which led to reports of many types of research on this versatile conjugated azide in recent years. This magical precursor can also be converted into intermediates such as iminyl radicals, 2-azirines, iminyl metal complexes, nitrilium ions, and iminyl ions, making this compound useful in heterocycle synthesis.

摘要

在有机叠氮化物中,乙烯基叠氮化物因其在有机合成中的独特性质而备受关注,这导致近年来有许多关于这种多功能共轭叠氮化物的各类研究报道。这种神奇的前体还可以转化为亚胺基自由基、2-氮杂环丙烷、亚胺基金属配合物、亚胺鎓离子和亚胺离子等中间体,使得该化合物在杂环合成中很有用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/538d/9811501/bbe99baa481b/d2ra06726a-f1.jpg

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