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基于环金属化铱（III）配合物的发光化学传感器及其应用

Luminescent chemosensors by using cyclometalated iridium(iii) complexes and their applications.

作者信息

Ma Dik-Lung, Lin Sheng, Wang Wanhe, Yang Chao, Leung Chung-Hang

机构信息

Department of Chemistry , Hong Kong Baptist University , Kowloon Tong , Hong Kong , China . Email:

State Key Laboratory of Quality Research in Chinese Medicine , Institute of Chinese Medical Sciences , University of Macau , Macao , China . Email:

出版信息

Chem Sci. 2017 Feb 1;8(2):878-889. doi: 10.1039/c6sc04175b. Epub 2016 Nov 2.

DOI:10.1039/c6sc04175b
PMID:28572899
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5452269/
Abstract

Luminescent metal complexes have found increasing use in multiple areas of science and technology, including in chemosensing, light-emitting devices and photochemistry. In particular, the use of cyclometalated iridium(iii) complexes as chemosensors has received increasing attention in the recent literature. Phosphorescent metal complexes enjoy a number of advantages (, long-lived phosphorescence, high quantum efficiency and modular syntheses) that render them as suitable alternatives to organic dyes for sensing a variety of analytes. This review describes recent examples of cyclometalated iridium(iii) complexes that act as luminescent chemosensors for cations, anions or small molecules.

摘要

发光金属配合物在多个科学技术领域的应用越来越广泛，包括化学传感、发光器件和光化学。特别是，近年来文献中，环金属化铱（III）配合物作为化学传感器的应用受到了越来越多的关注。磷光金属配合物具有许多优点（如长寿命磷光、高量子效率和模块化合成），使其成为用于检测各种分析物的有机染料的合适替代品。本文综述了近年来环金属化铱（III）配合物作为阳离子、阴离子或小分子发光化学传感器的实例。

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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78de/5452269/f0b43f65dc0a/c6sc04175b-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78de/5452269/7714d058f7bb/c6sc04175b-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78de/5452269/c00a368ed80d/c6sc04175b-f14.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/78de/5452269/914741f9a256/c6sc04175b-f15.jpg
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本文引用的文献

1
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J Mater Chem B. 2013 Jan 21;1(3):319-329. doi: 10.1039/c2tb00259k. Epub 2012 Nov 9.
2
Design principles of spectroscopic probes for biological applications.用于生物应用的光谱探针的设计原理。
Chem Sci. 2016 Oct 1;7(10):6309-6315. doi: 10.1039/c6sc02500e. Epub 2016 Jul 11.
3
An Ir(III) complex chemosensor for the detection of thiols.一种用于检测硫醇的铱（III）配合物化学传感器。
Sci Technol Adv Mater. 2016 Apr 6;17(1):109-114. doi: 10.1080/14686996.2016.1162081. eCollection 2016.
4
Intracellular and in vivo oxygen sensing using phosphorescent iridium(III) complexes.使用磷光铱（III）配合物进行细胞内和体内氧传感
Curr Opin Chem Biol. 2016 Aug;33:39-45. doi: 10.1016/j.cbpa.2016.05.017. Epub 2016 Jun 6.
5
Iridium(III) Anthraquinone Complexes as Two-Photon Phosphorescence Probes for Mitochondria Imaging and Tracking under Hypoxia.铱（III）蒽醌配合物作为用于缺氧条件下线粒体成像和追踪的双光子磷光探针。
Chemistry. 2016 Jun 20;22(26):8955-65. doi: 10.1002/chem.201600310. Epub 2016 May 4.
6
A Highly Selective Chemosensor for Cyanide Derived from a Formyl-Functionalized Phosphorescent Iridium(III) Complex.一种由甲酰基功能化磷光铱（III）配合物衍生的用于氰化物的高选择性化学传感器。
Inorg Chem. 2016 Apr 4;55(7):3448-61. doi: 10.1021/acs.inorgchem.5b02885. Epub 2016 Mar 23.
7
A long lifetime luminescent iridium(III) complex chemosensor for the selective switch-on detection of Al(3+) ions.一种用于选择性开启检测铝离子（Al(3+)）的长寿命发光铱（III）配合物化学传感器。
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8
A long lifetime switch-on iridium(III) chemosensor for the visualization of cysteine in live zebrafish.一种用于在活斑马鱼中可视化半胱氨酸的长寿命开启型铱(III)化学传感器。
Chem Commun (Camb). 2016 Mar 25;52(24):4450-3. doi: 10.1039/c6cc01008c.
9
A supramolecular H-bond driven light switch sensor for small anions.一种用于小阴离子的超分子氢键驱动光开关传感器。
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10
A sulfur-free iridium(III) complex for highly selective and multi-signaling mercury(II)-chemosensors.
Dalton Trans. 2015 Dec 14;44(46):19997-20003. doi: 10.1039/c5dt03129j.