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一种用于选择性开启检测铝离子(Al(3+))的长寿命发光铱(III)配合物化学传感器。

A long lifetime luminescent iridium(III) complex chemosensor for the selective switch-on detection of Al(3+) ions.

作者信息

Wang Wanhe, Mao Zhifeng, Wang Modi, Liu Li-Juan, Kwong Daniel W J, Leung Chung-Hang, Ma Dik-Lung

机构信息

Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China.

State Key Laboratory of Quality Research in Chinese Medicine, Institute of Chinese Medical Sciences, University of Macau, Macao, China.

出版信息

Chem Commun (Camb). 2016 Mar 4;52(18):3611-4. doi: 10.1039/c5cc10383e.

DOI:10.1039/c5cc10383e
PMID:26907607
Abstract

A novel luminescent cyclometalated iridium(III) complex was synthesized and employed as a chemosensor for the detection of Al(3+) ions. Compared with common organic chemosensors, displays a larger Stokes shift and a long lifetime luminescence that allow to detect Al(3+) ions in fluorescent dye spiked strong fluorescence media and potentially be used in strongly autofluorescent biological samples.

摘要

合成了一种新型的环金属化铱(III)发光配合物,并将其用作检测Al(3+)离子的化学传感器。与普通有机化学传感器相比,它具有更大的斯托克斯位移和长寿命发光,这使得它能够在荧光染料掺杂的强荧光介质中检测Al(3+)离子,并有可能用于强自发荧光的生物样品中。

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