通过合理修饰末端手性附属基团对吲哚并咔唑-吡啶杂化折叠体螺旋取向进行立体选择性控制。
Stereospecific control of the helical orientation of indolocarbazole-pyridine hybrid foldamers by rational modification of terminal chiral appendages.
作者信息
Kim Junyoung, Jeon Hae-Geun, Kang Philjae, Jeong Kyu-Sung
机构信息
Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
出版信息
Chem Commun (Camb). 2017 Jun 13;53(48):6508-6511. doi: 10.1039/c7cc03552g.
PMID:28573285
Abstract
The helical handedness excess of an indolocarbazole-pyridine hybrid oligomer capable of folding into a stable helical structure was achieved up to 96% by rational modification of terminal chiral residues.
摘要
通过对末端手性残基进行合理修饰，一种能够折叠成稳定螺旋结构的吲哚并咔唑 - 吡啶杂化低聚物的螺旋手性过量达到了96%。
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