• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

来自内稳态的单离子磁体中的可逆溶剂化磁开关

Reversible solvatomagnetic switching in a single-ion magnet from an entatic state.

作者信息

Vallejo J, Pardo E, Viciano-Chumillas M, Castro I, Amorós P, Déniz M, Ruiz-Pérez C, Yuste-Vivas C, Krzystek J, Julve M, Lloret F, Cano J

机构信息

Institut de Ciència Molecular (ICMOL) , Universitat de València , 46980 Paterna , València , Spain . Email:

Institut de Ciència del Materials (ICMUV) , Universitat de València , 46980 Paterna , València , Spain.

出版信息

Chem Sci. 2017 May 1;8(5):3694-3702. doi: 10.1039/c6sc05188j. Epub 2017 Feb 13.

DOI:10.1039/c6sc05188j
PMID:28580105
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5437488/
Abstract

A vast impact on molecular nanoscience can be achieved using simple transition metal complexes as dynamic chemical systems to perform specific and selective tasks under the control of an external stimulus that switches "ON" and "OFF" their electronic properties. While the interest in single-ion magnets (SIMs) lies in their potential applications in information storage and quantum computing, the switching of their slow magnetic relaxation associated with host-guest processes is insufficiently explored. Herein, we report a unique example of a mononuclear cobalt(ii) complex in which geometrical constraints are the cause of easy and reversible water coordination and its release. As a result, a reversible and selective colour and SIM behaviour switch occurs between a "slow-relaxing" deep red anhydrous material (compound ) and its "fast-relaxing" orange hydrated form (compound ). The combination of this optical and magnetic switching in this new class of vapochromic and thermochromic SIMs offers fascinating possibilities for designing multifunctional molecular materials.

摘要

使用简单的过渡金属配合物作为动态化学系统，在外部刺激的控制下执行特定和选择性任务，该刺激会“开启”和“关闭”其电子特性，这对分子纳米科学可产生巨大影响。虽然单离子磁体（SIMs）的潜在应用在于信息存储和量子计算，但其与主客体过程相关的缓慢磁弛豫的切换尚未得到充分探索。在此，我们报道了一个单核钴（II）配合物的独特例子，其中几何约束是水易于可逆配位及其释放的原因。结果，在“缓慢弛豫”的深红色无水材料（化合物）与其“快速弛豫”的橙色水合形式（化合物）之间发生了可逆且选择性的颜色和SIM行为切换。这种新型的气致变色和热致变色SIMs中这种光学和磁学切换的结合，为设计多功能分子材料提供了迷人的可能性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/214e43df0efe/c6sc05188j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/3244bb161b64/c6sc05188j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/14951bf06dc7/c6sc05188j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/e388a01b6e07/c6sc05188j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/106e64390bf0/c6sc05188j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/2eba16cc09a7/c6sc05188j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/0a3742d1faa4/c6sc05188j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/253c308b7239/c6sc05188j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/214e43df0efe/c6sc05188j-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/3244bb161b64/c6sc05188j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/14951bf06dc7/c6sc05188j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/e388a01b6e07/c6sc05188j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/106e64390bf0/c6sc05188j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/2eba16cc09a7/c6sc05188j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/0a3742d1faa4/c6sc05188j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/253c308b7239/c6sc05188j-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/248a/5437488/214e43df0efe/c6sc05188j-f8.jpg

相似文献

1
Reversible solvatomagnetic switching in a single-ion magnet from an entatic state.来自内稳态的单离子磁体中的可逆溶剂化磁开关
Chem Sci. 2017 May 1;8(5):3694-3702. doi: 10.1039/c6sc05188j. Epub 2017 Feb 13.
2
Reversible on-off switching of Dy(III) single-molecule magnets single-crystal-to-single-crystal transformation.镝（III）单分子磁体的可逆通断切换——单晶到单晶的转变。
Dalton Trans. 2022 May 3;51(17):6707-6717. doi: 10.1039/d2dt00501h.
3
Reversible solvatomagnetic switching in a spongelike manganese(II)-copper(II) 3D open framework with a pillared square/octagonal layer architecture.具有柱状方/八面体层结构的海绵状锰(II)-铜(II) 3D 开放式框架中的可逆溶剂化磁开关。
Chemistry. 2012 Feb 6;18(6):1608-17. doi: 10.1002/chem.201103308. Epub 2012 Jan 19.
4
pH-Switching of the luminescent, redox, and magnetic properties in a spin crossover cobalt(ii) molecular nanomagnet.自旋交叉钴（II）分子纳米磁体中发光、氧化还原和磁性的pH切换
Chem Sci. 2023 Jul 27;14(33):8850-8859. doi: 10.1039/d3sc02777e. eCollection 2023 Aug 23.
5
Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties.固态分子纳米磁体纳入磁性金属有机框架：磁性能的相互作用
Chemistry. 2016 Jan 11;22(2):539-45. doi: 10.1002/chem.201504176. Epub 2015 Nov 25.
6
Guest-dependent single-ion magnet behaviour in a cobalt(ii) metal-organic framework.钴（II）金属有机框架中依赖客体的单离子磁体行为
Chem Sci. 2016 Mar 1;7(3):2286-2293. doi: 10.1039/c5sc04461h. Epub 2015 Dec 10.
7
Reversible on-off switching of both spin crossover and single-molecule magnet behaviours a crystal-to-crystal transformation.自旋交叉和单分子磁体行为的可逆通断切换——一种晶对晶转变
Chem Sci. 2018 Aug 27;9(41):7986-7991. doi: 10.1039/c8sc02774a. eCollection 2018 Nov 7.
8
Supramolecular control over molecular magnetic materials: γ-cyclodextrin-templated grid of cobalt(II) single-ion magnets.超分子对分子磁性材料的控制：γ-环糊精模板化的钴（II）单离子磁体网格
Inorg Chem. 2014 Dec 15;53(24):12870-6. doi: 10.1021/ic501870h. Epub 2014 Nov 19.
9
Transition metal redox switches for reversible "on/off" and "slow/fast" single-molecule magnet behaviour in dysprosium and erbium bis-diamidoferrocene complexes.用于镝和铒双二氨基二茂铁配合物中可逆“开/关”和“慢/快”单分子磁行为的过渡金属氧化还原开关
Chem Sci. 2017 Dec 1;8(12):8039-8049. doi: 10.1039/c7sc03380j. Epub 2017 Oct 2.
10
A capped trigonal prismatic cobalt(ii) complex as a structural archetype for single-ion magnets.一种带帽三角棱柱形钴（II）配合物作为单离子磁体的结构原型。
Dalton Trans. 2020 Feb 21;49(7):2063-2067. doi: 10.1039/c9dt04881b. Epub 2020 Jan 30.

引用本文的文献

1
Cobalt(II) Single-Ion Magnet Coordinated by Double Deprotonation of 2,2'-Bipyridine-6,6'-diol Ligands.由2,2'-联吡啶-6,6'-二醇配体双去质子化配位的钴（II）单离子磁体
ACS Omega. 2024 Jun 6;9(24):26149-26158. doi: 10.1021/acsomega.4c01576. eCollection 2024 Jun 18.
2
pH-Switching of the luminescent, redox, and magnetic properties in a spin crossover cobalt(ii) molecular nanomagnet.自旋交叉钴（II）分子纳米磁体中发光、氧化还原和磁性的pH切换
Chem Sci. 2023 Jul 27;14(33):8850-8859. doi: 10.1039/d3sc02777e. eCollection 2023 Aug 23.
3
Air-stable four-coordinate cobalt(ii) single-ion magnets: experimental and ligand field analyses of correlations between dihedral angles and magnetic anisotropy.

本文引用的文献

1
Guest-dependent single-ion magnet behaviour in a cobalt(ii) metal-organic framework.钴（II）金属有机框架中依赖客体的单离子磁体行为
Chem Sci. 2016 Mar 1;7(3):2286-2293. doi: 10.1039/c5sc04461h. Epub 2015 Dec 10.
2
Two Polymorphic Forms of a Six-Coordinate Mononuclear Cobalt(II) Complex with Easy-Plane Anisotropy: Structural Features, Theoretical Calculations, and Field-Induced Slow Relaxation of the Magnetization.具有易面各向异性的六配位单核钴（II）配合物的两种多晶型：结构特征、理论计算及磁场诱导的磁化强度慢弛豫
Inorg Chem. 2016 Sep 6;55(17):8502-13. doi: 10.1021/acs.inorgchem.6b01087. Epub 2016 Aug 8.
3
Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties.
空气稳定的四配位钴（II）单离子磁体：二面角与磁各向异性之间相关性的实验与配体场分析
Chem Sci. 2023 May 12;14(23):6355-6374. doi: 10.1039/d3sc00813d. eCollection 2023 Jun 14.
4
Ultrafast Jahn-Teller Photoswitching in Cobalt Single-Ion Magnets.钴单离子磁体中的超快 Jahn-Teller 光开关效应
Adv Sci (Weinh). 2023 Jul;10(21):e2206880. doi: 10.1002/advs.202206880. Epub 2023 May 17.
5
Multi-Technique Experimental Benchmarking of the Local Magnetic Anisotropy of a Cobalt(II) Single-Ion Magnet.钴（II）单离子磁体局部磁各向异性的多技术实验基准测试
JACS Au. 2023 Jan 23;3(2):429-440. doi: 10.1021/jacsau.2c00575. eCollection 2023 Feb 27.
6
Multifunctional Properties of a 1D Helical Co(II) Coordination Polymer: Toward Single-Ion Magnetic Behavior and Efficient Dye Degradation.一维螺旋状钴（II）配位聚合物的多功能性质：迈向单离子磁行为及高效染料降解
ACS Omega. 2018 Nov 12;3(11):15315-15324. doi: 10.1021/acsomega.8b02212. eCollection 2018 Nov 30.
7
Reversible on-off switching of both spin crossover and single-molecule magnet behaviours a crystal-to-crystal transformation.自旋交叉和单分子磁体行为的可逆通断切换——一种晶对晶转变
Chem Sci. 2018 Aug 27;9(41):7986-7991. doi: 10.1039/c8sc02774a. eCollection 2018 Nov 7.
固态分子纳米磁体纳入磁性金属有机框架：磁性能的相互作用
Chemistry. 2016 Jan 11;22(2):539-45. doi: 10.1002/chem.201504176. Epub 2015 Nov 25.
4
Field-Induced Slow Magnetic Relaxation in a Mononuclear Manganese(III)-Porphyrin Complex.单核锰（III）-卟啉配合物中的场致慢磁弛豫
Chemistry. 2015 Nov 23;21(48):17299-307. doi: 10.1002/chem.201502637. Epub 2015 Oct 20.
5
A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior.三角棱柱单核钴(II)配合物表现出单分子磁体行为。
J Am Chem Soc. 2015 Aug 12;137(31):9792-5. doi: 10.1021/jacs.5b05739. Epub 2015 Jul 28.
6
A mononuclear Ni(ii) complex: a field induced single-molecule magnet showing two slow relaxation processes.一种单核镍（II）配合物：一种表现出两个慢弛豫过程的场诱导单分子磁体。
Dalton Trans. 2015 Jul 28;44(28):12484-7. doi: 10.1039/c5dt01213a. Epub 2015 Jun 12.
7
3d single-ion magnets.三维单离子磁体。
Chem Soc Rev. 2015 Apr 21;44(8):2135-47. doi: 10.1039/c4cs00439f.
8
Electronic structure and slow magnetic relaxation of low-coordinate cyclic alkyl(amino) carbene stabilized iron(I) complexes.低配位环状烷基（氨基）卡宾稳定的铁（I）配合物的电子结构和缓慢磁弛豫。
J Am Chem Soc. 2014 Aug 27;136(34):11964-71. doi: 10.1021/ja5043116. Epub 2014 Aug 13.
9
Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy.非单轴各向异性 Kramers 离子中缓慢磁弛豫的起源。
Nat Commun. 2014 Jul 1;5:4300. doi: 10.1038/ncomms5300.
10
Templated assembly of photoswitches significantly increases the energy-storage capacity of solar thermal fuels.模板组装光开关可显著提高太阳能热燃料的储能能力。
Nat Chem. 2014 May;6(5):441-7. doi: 10.1038/nchem.1918. Epub 2014 Apr 13.