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一种从灯笼树叶片中提取的新熊果苷衍生物。

A new arbutin derivative from the leaves of Vaccinium dunalianum wight.

作者信息

Li Na, Zeng Wei-Lin, Luo Xu-Lu, Yang Chong-Ren, Zhang Ying-Jun, Ding Yong, Zhao Ping

机构信息

a Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China , Ministry of Education, Southwest Forestry University , Kunming , China.

b State Key Laboratory of Phytochemistry and Plant Resources in West China , Kunming Institute of Botany, Chinese Academy of Sciences , Kunming , China.

出版信息

Nat Prod Res. 2018 Jan;32(1):65-70. doi: 10.1080/14786419.2017.1333993. Epub 2017 Jun 8.

Abstract

A new arbutin derivative, namely dunalianosides J (1), along with six known compounds, arbutin (2), robustaside A (3), 6'-O-caffeoylarbutin (4), dunalianoside D (5), kaempferol 3-O-β-D-glucopyranoside (6) and kaempferol 3-O-β-D-sambubioside (7) were isolated from the leaves of Vaccinium dunalianum Wight (Ericaceae). The structure of 1 was elucidated by extensive 1D and 2D NMR, HR-MS and CD spectroscopic analyses. In which, kaempferol 3-O-β-D-sambubioside (7) was isolated from the genus Vaccinium for the first time.

摘要

从越桔科植物灯笼草(Vaccinium dunalianum Wight)的叶子中分离得到一种新的熊果苷衍生物,即灯笼草苷J(1),以及六种已知化合物,熊果苷(2)、粗壮苷A(3)、6'-O-咖啡酰熊果苷(4)、灯笼草苷D(5)、山柰酚3-O-β-D-葡萄糖苷(6)和山柰酚3-O-β-D-接骨木二糖苷(7)。通过广泛的一维和二维核磁共振、高分辨质谱和圆二色光谱分析确定了1的结构。其中,山柰酚3-O-β-D-接骨木二糖苷(7)首次从越桔属植物中分离得到。

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