无过渡金属参与的 2,3-二（杂）芳基色满-4-酮的光诱导分子内环化反应
Transition-Metal-Free Photoinduced Intramolecular Annulation of 2,3-Di(hetero)arylchromen-4-one.
机构信息
Key Laboratory of the Ministry of Education for Medicinal Resources and Natural Pharmaceutical Chemistry, National Engineering Laboratory for Resource Development of Endangered Crude Drugs in Northwest of China, and School of Chemistry and Chemical Engineering, Shaanxi Normal University , Xi'an 710119, People's Republic of China.
出版信息
Org Lett. 2017 Jul 7;19(13):3552-3555. doi: 10.1021/acs.orglett.7b01531. Epub 2017 Jun 15.
An efficient transition-metal-free photoinduced intracyclization of 4H-chromen-4-ones in EtOH-HO (7:1, v/v) at ambient temperature for the construction of complicated fused-ring heteroaromatics is established. The reaction proceeds smoothly without requiring any catalysts/additives.
在室温下，在 EtOH-HO（7:1，v/v）中建立了一种高效的无过渡金属光诱导 4H-色烯-4-ones 的内环化反应，用于构建复杂的稠合环杂芳烃。该反应无需任何催化剂/添加剂即可顺利进行。
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