Zhang Tao, Schwedtmann Kai, Weigand Jan J, Doert Thomas, Ruck Michael
Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany.
Chem Commun (Camb). 2017 Jul 4;53(54):7588-7591. doi: 10.1039/c7cc03564k.
The dissolution behaviour of grey selenium in phosphonium based ionic liquids (ILs) has been investigated for the first time by P and Se nuclear magnetic resonance (NMR) experiments. The investigations evidence the formation of trialkylphosphane selenides which can serve as a selenium reservoir in the subsequent formation of metal selenides.
首次通过磷和硒核磁共振（NMR）实验研究了灰色硒在磷基离子液体（ILs）中的溶解行为。研究证明形成了三烷基膦硒化物，其可在随后金属硒化物的形成过程中作为硒储存库。
