一种通过氧化还原活性配体框架支持的制备同核和异核5f-5f及3d-5f配合物的通用方法。
A versatile route to homo- and hetero-bimetallic 5f-5f and 3d-5f complexes supported by a redox active ligand framework.
作者信息
Camp Clément, Toniolo Davide, Andrez Julie, Pécaut Jacques, Mazzanti Marinella
机构信息
Univ. Grenoble Alpes, INAC-SyMMES, F-38000 Grenoble, France.
出版信息
Dalton Trans. 2017 Aug 29;46(34):11145-11148. doi: 10.1039/c7dt01993a.
PMID:28650052
Abstract
The salt-elimination reaction of the complex [NaU(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium-uranium and rare heterobimetallic uranium-cobalt and uranium-nickel complexes supported by a redox-active dinucleating ligand.
摘要
配合物[NaU(bis-salophen)]与金属卤化物的脱盐反应为合成由氧化还原活性双核配体支撑的结构明确的同双核铀-铀以及罕见的异双核铀-钴和铀-镍配合物提供了途径。
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