从三核簇到一维链的可逆晶体到晶体转变以及相应的自旋交叉（SCO）行为变化。
Reversible crystal-to-crystal transformation from a trinuclear cluster to a 1D chain and the corresponding spin crossover (SCO) behaviour change.
作者信息
Chen Wen-Bin, Leng Ji-Dong, Wang Zi-Zhou, Chen Yan-Cong, Miao Yu, Tong Ming-Liang, Dong Wen
机构信息
Guangzhou Key Laboratory for Environmentally Functional Materials and Technology, School of Chemistry and Chemical Engineering, Guangzhou University, 230 Wai Huan Xi Road, Guangzhou Higher Education Mega Center, Guangzhou 510006, P. R. China.
出版信息
Chem Commun (Camb). 2017 Jul 6;53(55):7820-7823. doi: 10.1039/c7cc04036a.
Reversible crystal-to-crystal transformation between a linear trinuclear Fe(ii) complex [Fe(NH-trz)(SCN)(HO)] (SCN)·4HO (1, NH-trz = 4-amino-1,2,4-triazole) and a 1D chain Fe(NH-trz)(SCN) (1a) and the SCO behaviour change have been studied by X-ray single-crystal diffraction, magnetic measurements and DSC. Complex 1a exhibits one more SCO step at a low temperature.
通过X射线单晶衍射、磁性测量和差示扫描量热法研究了线性三核铁（II）配合物[Fe(NH-trz)(SCN)(HO)] (SCN)·4HO（1，NH-trz = 4-氨基-1,2,4-三唑）与一维链状配合物Fe(NH-trz)(SCN)（1a）之间可逆的晶体到晶体转变以及自旋交叉行为变化。配合物1a在低温下表现出多一个自旋交叉步骤。
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