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一种通过改变镧系元素配合物荧光颜色来检测乙酸乙酯的高灵敏度传感器。

A highly sensitive sensor for ethyl acetate by changing fluorescent colour of lanthanide complex.

作者信息

Zhao Lina

机构信息

Department of Food & Environmental Engineering, East University of Heilongjiang, Harbin, People's Republic of China.

出版信息

Luminescence. 2017 Sep;32(6):1109-1112. doi: 10.1002/bio.3355. Epub 2017 Jun 27.

Abstract

A lanthanide complex, namely, [La (L-DBTA) (CH OH) (H O) ]∙2H2O has been synthesized using a simple reaction of L-O,O´-dibenzoyl tartaric acid with LaCl ∙6H O under ambient temperature. The luminescence spectrum in the solid state at room temperature revealed that the complex exhibited blue-light emission that originated from ligand. In addition, the lanthanide complex is developed as a fluorescent probe for sensing small molecules. Luminescence studies reveal that the lanthanide complex could detect ethyl acetate sensitively through fluorescence colour change from blue to yellow. Furthermore, the complex exhibited appealing features including high sensitivity and an ultrafast response.

摘要

一种镧系配合物,即[La (L-DBTA) (CH₂OH) (H₂O)₂]∙2H₂O,已通过L-O,O´-二苯甲酰酒石酸与LaCl₃∙6H₂O在室温下的简单反应合成。室温下固态的发光光谱表明该配合物表现出源于配体的蓝光发射。此外,该镧系配合物被开发为一种用于传感小分子的荧光探针。发光研究表明,该镧系配合物可通过荧光颜色从蓝色变为黄色来灵敏地检测乙酸乙酯。此外,该配合物具有高灵敏度和超快响应等吸引人的特性。

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