萘醌的分子内光氧化还原反应的立体专一性：(-)-螺环辛可宁 C 的对映选择性全合成。
Stereospecificity in Intramolecular Photoredox Reactions of Naphthoquinones: Enantioselective Total Synthesis of (-)-Spiroxin C.
机构信息
Department of Chemistry, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro, Tokyo, 152-8551, Japan.
出版信息
Angew Chem Int Ed Engl. 2017 Sep 11;56(38):11460-11465. doi: 10.1002/anie.201705562. Epub 2017 Aug 7.
PMID:28671750
Abstract
Intramolecular photoredox reactions of naphthoquinone derivatives were found to proceed in a stereospecific manner. This method was used as a basis for the enantioselective total synthesis of (-)-spiroxin C.
摘要
萘醌衍生物的分子内光氧化还原反应被发现以立体特异性的方式进行。该方法被用作（-）-螺环辛可宁 C 的对映选择性全合成的基础。
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