Ghatak Tapas, Drucker Shani, Fridman Natalia, Eisen Moris S
Schulich Faculty of Chemistry, Technion - Israel Institute of Technology, Technion Haifa, 32000, Israel.
Dalton Trans. 2017 Sep 28;46(36):12005-12009. doi: 10.1039/c7dt02126g. Epub 2017 Jul 5.
Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp*Th(L)(CH). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.
引入了六元和七元氮杂环亚氨基配体（L），从而可以合成一类新型的Cp*Th（L）（CH）型钍（IV）配合物。对这些配合物进行了坎尼扎罗反应研究。化学计量反应以及动力学和热力学研究使我们能够提出一个合理的反应机理。
