Department of Chemical Engineering and Materials Science, University of Minnesota , 421 Washington Avenue SE, Minneapolis, Minnesota 55455-0132, United States.
Department of Chemistry and Chemical Theory Center, University of Minnesota , 207 Pleasant Street SE, Minneapolis, Minnesota 55455-0431, United States.
Chem Rev. 2017 Jul 26;117(14):9755-9803. doi: 10.1021/acs.chemrev.7b00095. Epub 2017 Jul 5.
Hydrogen sulfide removal is a long-standing economic and environmental challenge faced by the oil and gas industries. HS separation processes using reactive and non-reactive absorption and adsorption, membranes, and cryogenic distillation are reviewed. A detailed discussion is presented on new developments in adsorbents, such as ionic liquids, metal oxides, metals, metal-organic frameworks, zeolites, carbon-based materials, and composite materials; and membrane technologies for HS removal. This Review attempts to exhaustively compile the existing literature on sour gas sweetening and to identify promising areas for future developments in the field.
硫化氢脱除是石油和天然气工业面临的一个长期存在的经济和环境挑战。本文综述了使用反应性和非反应性吸收和吸附、膜和低温蒸馏的 HS 分离工艺。详细讨论了吸附剂(如离子液体、金属氧化物、金属、金属有机骨架、沸石、碳基材料和复合材料)和用于 HS 去除的膜技术的新进展。本综述试图详尽地收集关于酸性气体脱硫的现有文献,并确定该领域未来发展的有前途的领域。