Department of Material Chemistry, Graduate School of Engineering, Kyoto University , Nishikyo-ku, Kyoto 615-8510, Japan.
Fukui Institute for Fundamental Chemistry, Kyoto University , Sakyo-ku, Kyoto 606-8103, Japan.
J Am Chem Soc. 2017 Jul 19;139(28):9423-9426. doi: 10.1021/jacs.7b03159. Epub 2017 Jul 5.
Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO) bond by palladium, which represents an unprecedented elemental reaction.
通过使用硝基芳烃作为亲电偶联伙伴的 Suzuki-Miyaura 偶联（SMC）反应合成联芳烃。机理研究表明，该反应的催化循环是由钯催化断裂芳基-硝基（Ar-NO）键引发的，这代表了一种前所未有的元素反应。
