Knipe Peter C, Thompson Sam, Hamilton Andrew D
Department of Chemistry , Chemistry Research Laboratory , University of Oxford , 12 Mansfield Road , Oxford OX1 3TA , UK . Email:
Chem Sci. 2015 Mar 1;6(3):1630-1639. doi: 10.1039/c4sc03525a. Epub 2014 Nov 21.
Molecular switches are ubiquitous in Nature and provide the basis of many forms of transport and signalling. synthetic molecules that change conformation, and thus function, reversibly in a stimulus-dependent manner are of great interest not only to chemists but society in general; myriad applications exist in storage, display, sensing and medicine. Here we describe recent developments in the area of -mediated switching.
分子开关在自然界中无处不在,是多种运输和信号传导形式的基础。能够以刺激依赖的方式可逆地改变构象进而改变功能的合成分子不仅引起了化学家的极大兴趣,也受到了整个社会的广泛关注;在存储、显示、传感和医学等领域有着无数的应用。在此,我们描述了在介导开关领域的最新进展。