Univ Lyon, Ens de Lyon, Univ Claude Bernard Lyon 1, CNRS, Laboratoire de Physique, F-69342, Lyon, France.
J Colloid Interface Sci. 2017 Nov 1;505:1118-1124. doi: 10.1016/j.jcis.2017.06.095. Epub 2017 Jun 29.
The capillary force in situations where the liquid meniscus is asymmetric, such as the one around a tilted object, has been hitherto barely investigated even though these situations are very common in practice. In particular, the capillary force exerted on a tilted object may depend on the dipping angle i.
We investigate experimentally the capillary force that applies on a tilted cylinder as a function of its dipping angle i, using a home-built tilting Atomic Force Microscope (AFM) with custom made probes. A micrometric-size rod is glued at the end of an AFM cantilever of known stiffness, whose deflection is measured when the cylindrical probe is dipped in and retracted from reference liquids.
We show that a torque correction is necessary to understand the measured deflection. We give the explicit expression of this correction as a function of the probes' geometrical parameters, so that its magnitude can be readily evaluated. The results are compatible with a vertical capillary force varying as 1/cosi, in agreement with a recent theoretical prediction. Finally, we discuss the accuracy of the method for measuring the surface tension times the cosine of the contact angle of the liquid on the probe.
在液体弯月面不对称的情况下,例如在倾斜物体周围,毛细力迄今几乎没有被研究过,尽管这些情况在实践中非常普遍。特别是,倾斜物体上的毛细力可能取决于浸入角 i。
我们使用自制的倾斜原子力显微镜(AFM)和定制的探头,实验研究了作为倾斜角 i 的函数的倾斜圆柱体上的毛细力。将一个微米级大小的杆粘在已知刚度的 AFM 悬臂的末端,当圆柱形探头浸入和从参考液体中缩回时,测量探针的挠度。
我们表明,为了理解测量的挠度,需要进行扭矩修正。我们给出了该修正的显式表达式,作为探头几何参数的函数,因此可以很容易地评估其大小。结果与最近的理论预测一致,表明垂直毛细力随 1/cosi 变化。最后,我们讨论了测量探针上液体的表面张力乘以接触角余弦的方法的准确性。