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在混合溶剂中无模板和表面活性剂合成超薄CeO纳米线及其在水处理中的卓越吸附能力。

Template- and surfactant-free synthesis of ultrathin CeO nanowires in a mixed solvent and their superior adsorption capability for water treatment.

作者信息

Yu Xiao-Fang, Liu Jian-Wei, Cong Huai-Ping, Xue Lei, Arshad Muhammad Nadeem, Albar Hassan A, Sobahi Tariq R, Gao Qiang, Yu Shu-Hong

机构信息

Division of Nanomaterials and Chemistry , Hefei National Laboratory for Physical Sciences at Microscale , Department of Chemistry , University of Science and Technology of China , Hefei , Anhui 230026 , P. R. China . Email:

Center of Excellence for Advanced Materials Research , Chemistry Department , Faculty of Science , King Abdulaziz University , Jeddah 21589 , Saudi Arabia.

出版信息

Chem Sci. 2015 Apr 16;6(4):2511-2515. doi: 10.1039/c5sc00104h. Epub 2015 Feb 16.

Abstract

Ultrathin CeO nanowires with a diameter of 5 nm and an aspect ratio of more than 100 can be prepared by a one-step refluxing approach in a mixed solvent composed of water and ethanol without using any templates or surfactants. The formation mechanism of the as-synthesized ultrathin nanowires has been investigated. The as-synthesized CeO nanowires with a high surface area of 125.31 m g exhibited excellent wastewater treatment performance with high removal capacities towards organic dyes and heavy metal ions. In addition, the as-synthesized CeO nanowires can adsorb Congo red selectively from a mixed solution composed of several dyes. Successful access to high quality ultrathin nanowires will make it possible for their potential application in catalysis and other fields.

摘要

直径为5纳米且长径比超过100的超薄氧化铈纳米线可以通过在由水和乙醇组成的混合溶剂中一步回流法制备,无需使用任何模板或表面活性剂。已对合成的超薄纳米线的形成机理进行了研究。合成的氧化铈纳米线具有125.31 m²/g的高比表面积,对有机染料和重金属离子具有高去除能力,表现出优异的废水处理性能。此外,合成的氧化铈纳米线可以从几种染料组成的混合溶液中选择性吸附刚果红。成功制备高质量的超薄纳米线将使其在催化等领域的潜在应用成为可能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9988/5489027/a4bfac9d21ed/c5sc00104h-f1.jpg

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