Minari Guilherme Deomedesse, Rosalen David Luciano, da Cruz Mara Cristina Pessôa, de Melo Wanderley José, Alves Lucia Maria Carareto, Saran Luciana Maria
Technology Department, São Paulo State University (UNESP), School of Agricultural and Veterinarian Sciences, Acesso Prof. Paulo Donato Castellane, S/N, 14884-900, Jaboticabal, SP, Brazil.
Rural Engineering Department, São Paulo State University (UNESP), School of Agricultural and Veterinarian Sciences, Acesso Prof. Paulo Donato Castellane, S/N, 14884-900, Jaboticabal, SP, Brazil.
Chemosphere. 2017 Oct;185:344-350. doi: 10.1016/j.chemosphere.2017.07.008. Epub 2017 Jul 3.
Soil contamination may result from the inadequate disposal of substances with polluting potential or prolonged agricultural use. Therefore, cadmium (Cd), chromium (Cr) and nickel (Ni) concentrations were assessed in a Eutroferric Red Oxisol under a no-tillage farming system with mineral fertilizer applications, a conventional tillage system with mineral fertilizer application and a conventional tillage system with sewage sludge application in an area used for agriculture for more than 80 years. We evaluated the spatial distributions of these elements in the experimental area and the effect of the different management practices on the soil retention of these metals. The concentrations of metals extracted from 422 soil samples by open-system digestion with HNO, HO and HCl were assessed by flame atomic absorption spectroscopy. The pH and soil organic matter were also assessed, and spatial distribution maps were designed. The mean concentrations of Cd, Cr and Ni (1.0, 50 and 14 mg kg, respectively) in the native forest were higher than the reference values (100, 25 and 8% greater, respectively) in Brazilian legislation, indicating that the source material was the determining factor of the high metal concentrations in the study soils. Soil management with sewage sludge was the major contributor to the accumulation of Cd and Ni, whereas Cr concentration did not vary with management type. Approximately 0.3, 12 and 16% of the experimental area is contaminated with Ni, Cd and Cr, respectively, because their concentrations exceeded the values for alertness or prevention in Brazilian legislation.
土壤污染可能源于具有污染潜力的物质处置不当或长期的农业利用。因此,在一个使用矿物肥料的免耕种植系统、一个使用矿物肥料的传统耕作系统以及一个在已用于农业80多年的区域使用污水污泥的传统耕作系统下,对富铁氧化土中的镉(Cd)、铬(Cr)和镍(Ni)浓度进行了评估。我们评估了这些元素在试验区的空间分布以及不同管理措施对这些金属在土壤中保留的影响。通过用硝酸、过氧化氢和盐酸进行开放系统消解从422个土壤样品中提取的金属浓度,采用火焰原子吸收光谱法进行评估。还评估了土壤pH值和有机质,并绘制了空间分布图。原生森林中Cd、Cr和Ni的平均浓度(分别为1.0、50和14毫克/千克)高于巴西法规中的参考值(分别高出100%、25%和8%),这表明源材料是研究土壤中高金属浓度的决定性因素。使用污水污泥进行土壤管理是Cd和Ni积累的主要原因,而Cr浓度不随管理类型而变化。分别约有0.3%、12%和16%的试验区被Ni、Cd和Cr污染,因为它们的浓度超过了巴西法规中的警戒或预防值。