Energy Migration Upconversion in Ce(III)-Doped Heterogeneous Core-Shell-Shell Nanoparticles.

One major challenge in upconversion research is to develop new materials and structures to expand the emission spectrum. Herein, a heterogeneous core-shell-shell nanostructure of NaYbF :Gd/Tm@NaGdF @CaF :Ce is developed to realize efficient photon upconversion in Ce ions through a Gd-mediated energy migration process. The design takes advantage of CaF host that reduces the 4f-5d excitation frequency of Ce to match the emission line of Gd . Meanwhile, CaF is isostructural with NaGdF and can form a continuous crystalline lattice with the core layer. As a result, effective Yb → Tm → Gd → Ce energy transfer can be established in a single nanoparticle. This effect enables efficient ultraviolet emission of Ce following near infrared excitation into the core layer. The Ce upconversion emission achieved in the core-shell-shell nanoparticles features broad bandwidth and long lifetime, which offers exciting opportunities of realizing tunable lasing emissions in the ultraviolet spectral region.