Biorefining Research Institute, Lakehead University, 1294 Balmoral Street, Thunder Bay, Ontario P7B5Z5, Canada.
Biorefining Research Institute, Lakehead University, 1294 Balmoral Street, Thunder Bay, Ontario P7B5Z5, Canada.
Carbohydr Polym. 2017 Oct 1;173:253-258. doi: 10.1016/j.carbpol.2017.06.005. Epub 2017 Jun 3.
Although cellulosic fibers are increasingly used in textile products, current methods for production of cellulose-based textiles suffer certain economic and/or environmental drawbacks. We have developed a new, cost-effective and environmentally-friendly (CS-free) process that overcomes some of the shortcomings of existing technologies. The process is based on a modified method for periodate oxidation of cellulose that is then cross-linked with chitosan and extruded to obtain cellulosic fibers in the form of textile fibers. The produced fibers have low content of aldehyde groups (∼2mmol/g cellulose) and water retention values of 1.5-2.0g/g fibers. The new process makes use of both hardwood and softwood pulps, and offers significant yield advantages over the use of dissolving pulp as a raw material. The mechanical, water absorbency and morphological properties of the new textile fibers and their potential applications are discussed. The potential techno-economic and environmental benefits of the process are summarized.
尽管纤维素纤维在纺织品中的应用日益广泛,但目前生产基于纤维素的纺织品的方法存在一定的经济和/或环境缺陷。我们开发了一种新的、具有成本效益和环保效益的(无 CS)工艺,克服了现有技术的一些缺点。该工艺基于对纤维素进行高碘酸盐氧化的改良方法,然后用壳聚糖进行交联,并挤出获得纤维素纤维,其形式为纺织纤维。所生产的纤维的醛基含量低(~2mmol/g 纤维素),保水值为 1.5-2.0g/g 纤维。新工艺可同时利用硬木和软木浆,并相对于使用溶解浆作为原料具有显著的产量优势。讨论了新型纺织纤维的机械性能、吸水性和形态性能及其潜在应用。总结了该工艺的潜在技术经济和环境效益。