Department of Physics, Nanchang University, Nanchang, 330031, China.
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD, 20742, USA.
Sci Rep. 2017 Jul 24;7(1):6289. doi: 10.1038/s41598-017-06615-z.
We study the performance of a cyclic heat engine which uses a small system with a finite number of ultracold atoms as its working substance and works between two heat reservoirs at constant temperatures T and T (<T ). Starting from the expression of heat capacity which includes finite-size effects, the work output is optimized with respect to the temperature of the working substance at a special instant along the cycle. The maximum-work efficiency η at small relative temperature difference can be expanded in terms of the Carnot value [Formula: see text], [Formula: see text], where a is a function depending on the particle number N and becomes vanishing in the symmetric case. Moreover, we prove using the relationship between the temperatures of the working substance and heat reservoirs that the maximum-work efficiency, when accurate to the first order of η , reads Formula: see text. Within the framework of linear irreversible thermodynamics, the maximum-power efficiency is obtained as Formula: see text through appropriate identification of thermodynamic fluxes and forces, thereby showing that this kind of cyclic heat engines satisfy the tight-coupling condition.
我们研究了一种循环热机的性能,该热机使用一个带有有限数量超冷原子的小系统作为工作物质,在两个恒温热库之间工作,温度分别为 T 和 T (<T )。从包含有限尺寸效应的热容表达式出发,我们针对工作物质在循环过程中某一特殊瞬间的温度对输出功进行了优化。在小相对温度差的情况下,最大功效率 η 可以展开为卡诺值[Formula: see text]、[Formula: see text],其中 a 是一个依赖于粒子数 N 的函数,在对称情况下趋于零。此外,我们使用工作物质和热库温度之间的关系证明,最大功效率,精确到 η 的一阶,为[Formula: see text](ΔT )。在线性不可逆热力学框架内,通过适当的热力学流和力的识别,得到最大功率效率为[Formula: see text](ΔT ),从而表明这种循环热机满足紧耦合条件。