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Synthesis of 1,2-Bis(trifluoromethylthio)arenes via Aryne Intermediates.
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General method for functionalized polyaryl synthesis via aryne intermediates.
J Am Chem Soc. 2014 Jun 18;136(24):8568-76. doi: 10.1021/ja504886x. Epub 2014 Jun 3.
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1,2-Bis(arylthio)arene synthesis via aryne intermediates.
Chem Commun (Camb). 2019 Aug 7;55(64):9467-9470. doi: 10.1039/c9cc03863a.
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New Hindered Amide Base for Aryne Insertion into Si-P, Si-S, Si-N, and C-C Bonds.
J Am Chem Soc. 2018 Oct 24;140(42):13703-13710. doi: 10.1021/jacs.8b07064. Epub 2018 Oct 10.
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Employing Arynes in Diels-Alder Reactions and Transition-Metal-Free Multicomponent Coupling and Arylation Reactions.
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Synthesis of the bis-spiroacetal moiety of spirolides B and D.
Org Lett. 2005 Aug 4;7(16):3497-500. doi: 10.1021/ol051260u.
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Transition-metal-free C-S bond formation: a facile access to aryl sulfones from sodium sulfinates via arynes.
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New synthesis of spirocycles by utilizing in situ forming hypervalent iodine species.
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1
Bromothiolation of Arynes for the Synthesis of 2-Bromobenzenethiol Equivalents.
Org Lett. 2024 May 10;26(18):3816-3821. doi: 10.1021/acs.orglett.4c00944. Epub 2024 Apr 30.
2
Cascade trifluoromethylthiolation and cyclization of -[(3-aryl)propioloyl]indoles.
Beilstein J Org Chem. 2020 Apr 8;16:657-662. doi: 10.3762/bjoc.16.62. eCollection 2020.
3
1,2-Bis(arylthio)arene synthesis via aryne intermediates.
Chem Commun (Camb). 2019 Aug 7;55(64):9467-9470. doi: 10.1039/c9cc03863a.
4
Copper-mediated 1,2-bis(trifluoromethylation) of arynes.
Chem Sci. 2018 Sep 21;9(47):8871-8875. doi: 10.1039/c8sc03754j. eCollection 2018 Dec 21.

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1
Arylazoindazole Photoswitches: Facile Synthesis and Functionalization via SAr Substitution.
J Am Chem Soc. 2017 Mar 8;139(9):3328-3331. doi: 10.1021/jacs.6b12585. Epub 2017 Feb 24.
2
Silylaryl Halides Can Replace Triflates as Aryne Precursors.
Org Lett. 2016 Aug 5;18(15):3910-3. doi: 10.1021/acs.orglett.6b01952. Epub 2016 Jul 14.
3
Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers.
Angew Chem Int Ed Engl. 2016 Aug 8;55(33):9758-62. doi: 10.1002/anie.201604793. Epub 2016 Jul 7.
4
Acidity of Strong Acids in Water and Dimethyl Sulfoxide.
J Phys Chem A. 2016 May 26;120(20):3663-9. doi: 10.1021/acs.jpca.6b02253. Epub 2016 May 6.
5
Silver-Mediated Trifluoromethylthiolation-Iodination of Arynes.
Org Lett. 2016 Feb 19;18(4):856-9. doi: 10.1021/acs.orglett.6b00142. Epub 2016 Feb 5.
6
General method for functionalized polyaryl synthesis via aryne intermediates.
J Am Chem Soc. 2014 Jun 18;136(24):8568-76. doi: 10.1021/ja504886x. Epub 2014 Jun 3.
7
8
Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction.
Science. 2013 Nov 22;342(6161):956-60. doi: 10.1126/science.1243759.
9
Cu(OTf)2-mediated fluorination of aryltrifluoroborates with potassium fluoride.
J Am Chem Soc. 2013 Nov 6;135(44):16292-5. doi: 10.1021/ja408607r.

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