Department of Chemical & Biomolecular Engineering and ‡Department of Civil & Environmental Engineering, National University of Singapore , Singapore 117585, Singapore.
Environ Sci Technol. 2017 Sep 5;51(17):10041-10049. doi: 10.1021/acs.est.7b01494. Epub 2017 Aug 15.
Severe air pollution has become a global concern, and there is a pressing need to develop effective and efficient air filters for removing airborne particulate matters (PMs). In this work, a highly permeable poly(ether sulfone) (PES) based hollow fiber membrane was developed via a one-step dry-jet wet spinning. For the first time, a hollow fiber membrane was used in removing the ultrafine particles (PMs with aerodynamic equivalent diameters of less than 100 nm) in PM. The novel air filter was designed to possess the synergistic advantages of porous filters and fibrous filters with a sievelike outer surface and a fibrouslike porous substrate. A filtration efficiency of higher than 99.995% could be easily achieved when the self-support hollow fiber was challenged with less than 300 nm particulates. Without losses of the structural advantages, we have demonstrated that the permeation properties of the hollow fiber membrane can be facilely tailored via manipulation of the dope and bore fluid formulations. Various cleaning strategies were explored to regenerate the membrane performance after fouling. Both water rinse and backwash showed effectiveness to restore the membrane permeance for repetitive usage.
严重的空气污染已经成为全球性的关注焦点,因此迫切需要开发高效能的空气过滤器以去除空气中的颗粒物。在这项工作中,我们通过一步法干喷湿纺工艺制备了高通量的聚醚砜(PES)中空纤维膜。首次将中空纤维膜应用于去除 PM 中粒径小于 100nm 的超细颗粒物(空气动力学等效直径小于 100nm 的颗粒物)。新型空气过滤器的设计结合了多孔过滤器和纤维过滤器的协同优势,具有筛网状外表面和纤维状多孔基底。当自支撑中空纤维膜遇到小于 300nm 的颗粒物时,很容易实现过滤效率高于 99.995%。在不损失结构优势的情况下,我们已经证明可以通过改变纺丝液和芯液的组成来轻松调整中空纤维膜的渗透性能。探索了各种清洗策略来在膜污染后对其进行再生。水冲洗和反冲洗都能有效地恢复膜的渗透性,以实现重复使用。