Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China.
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China.
Mar Pollut Bull. 2017 Nov 15;124(1):139-146. doi: 10.1016/j.marpolbul.2017.06.083. Epub 2017 Jul 26.
Simulated column was applied to research forming progress of single oil droplet in submerged process, floating progress, and study effects of environment factors and dispersants on the concentration of oil hydrocarbon in water as well as changing rules of oil droplet sizes. As expected, particular formation mechanism of single oil droplet was presented. When necking down length L is 0.5 time of oil droplet diameter (d) after expansion phase, necking down becomes long and thin; when L=2d, necking down begins to break. In floating progress, the shape changes oval and its motion trail becomes an auger-type. Fluctuation occurs at horizontal direction. Dispersants decrease oil droplet size by its dispersion effect, and cut down effect of Van Der Waals force among oil droplets. More broadly, these findings provide rare empirical evidence expounding formation mechanism of single oil droplet to increasing ability of oil spill response.
模拟柱被应用于研究水下过程中单油滴的形成过程、上浮过程,以及环境因素和分散剂对水中油类碳氢化合物浓度的影响,以及油滴大小的变化规律。预期的是,提出了单油滴的特定形成机制。当颈缩长度 L 为膨胀阶段后油滴直径 (d) 的 0.5 倍时,颈缩变得又长又细;当 L=2d 时,颈缩开始断裂。在上浮过程中,形状变为椭圆形,运动轨迹呈螺旋状。在水平方向上发生波动。分散剂通过其分散作用和减少油滴之间范德华力的切割作用来减小油滴的尺寸。更广泛地说,这些发现为提高溢油应急能力提供了单油滴形成机制的罕见经验证据。