State Key Laboratory of Food Science and Technology, Jiangnan University , Wuxi 214122, P. R. China.
School of Food Science and Technology, Jiangnan University , Wuxi 214122, P. R. China.
ACS Appl Mater Interfaces. 2017 Aug 23;9(33):27727-27735. doi: 10.1021/acsami.7b07657. Epub 2017 Aug 15.
Porous g-CN nanosheet (PCNS) photocatalyst with a thickness of 2.0 nm, pore volume of 0.61 cm g, and surface area of 190.1 m g was prepared by a simple two-step template-free approach without the addition of extra reagents. Compared with the bulk g-CN (BCN), PCNS possesses a greater number of surface reactive sites, improved efficiency of charge transfer, and accelerated separation of photogenerated electron-hole pairs. Accordingly, the visible-light-driven photocatalytic disinfection performance and organic pollutant degradation activity of PCNS are significantly enhanced. Escherichia coli (E. coli) cells can be killed completely by PCNS within 4 h, whereas only 77.1% of E. coli cells can be killed by BCN. The photodegradation rates of PCNS on methylene blue, Acid Red 27, and bisphenol A are almost 6.4, 4.0, and 1.9 times as fast as that of BCN, respectively. The photocurrent intensity of PCNS is about 3.7 times in comparison with that of BCN. Considering the easy preparation and excellent performance, PCNS could be a promising and competitive visible-light-driven photocatalyst in the field of environment remediation.
多孔 g-CN 纳米片(PCNS)光催化剂的厚度为 2.0nm,孔体积为 0.61cm³/g,比表面积为 190.1m²/g,采用简单的两步无模板方法制备,无需添加额外的试剂。与体相 g-CN(BCN)相比,PCNS 具有更多的表面反应活性位、提高的电荷转移效率和加速的光生电子-空穴对分离。因此,PCNS 的可见光驱动光催化消毒性能和有机污染物降解活性得到显著增强。PCNS 在 4 小时内可完全杀死大肠杆菌(E. coli)细胞,而 BCN 只能杀死 77.1%的 E. coli 细胞。PCNS 对亚甲基蓝、酸性红 27 和双酚 A 的光降解速率分别是 BCN 的 6.4、4.0 和 1.9 倍。PCNS 的光电流强度约为 BCN 的 3.7 倍。考虑到其易于制备和优异的性能,PCNS 有望成为环境修复领域一种有前途和竞争力的可见光驱动光催化剂。