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基于静电纺丝聚丙烯腈纳米纤维支架的高通量超滤膜用于从水溶液中去除砷酸盐。

High-flux ultrafiltration membrane based on electrospun polyacrylonitrile nanofibrous scaffolds for arsenate removal from aqueous solutions.

机构信息

Environmental Health Research Center, Kurdistan University of Medical Sciences, Sanandaj, Iran.

Faculty of Engineering, University of Kurdistan, Sanandaj, Iran.

出版信息

J Colloid Interface Sci. 2017 Nov 15;506:564-571. doi: 10.1016/j.jcis.2017.07.086. Epub 2017 Jul 24.

DOI:10.1016/j.jcis.2017.07.086
PMID:28759856
Abstract

Arsenic contamination in drinking water is a serious problem worldwide. In this study, to remove arsenate from contaminated water, a new thin-film composite (TFC) membrane was fabricated and tested. This membrane was composed of an electrospun nanofibrous scaffold, a polyethylene terephthalate (PET) substrate as support, and a polyacrylonitrile (PAN) coating layer. To effectively reject arsenate ions, cetylpyridinium chloride (CPC) pretreatment was used. For evaluating the performance of TFC membrane, its flux and contaminant rejection were compared to a conventional ultrafiltration (UF) membrane. Due to high porosity, the TFC membrane showed a flux, which was 172-520% higher than the UF membrane. In addition, The TFC membrane was 1.1-1.3 times more efficient in rejecting arsenate ions than the UF membrane.

摘要

饮用水中的砷污染是一个全球性的严重问题。在这项研究中,为了去除受污染水中的砷酸盐,我们制备并测试了一种新型的薄膜复合(TFC)膜。该膜由静电纺纳米纤维支架、聚对苯二甲酸乙二醇酯(PET)基底和聚丙烯腈(PAN)涂层组成。为了有效地去除砷酸盐离子,我们使用了十六烷基氯化吡啶(CPC)预处理。为了评估 TFC 膜的性能,我们将其通量和污染物去除率与传统的超滤(UF)膜进行了比较。由于高孔隙率,TFC 膜的通量比 UF 膜高 172-520%。此外,TFC 膜去除砷酸盐离子的效率比 UF 膜高 1.1-1.3 倍。

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