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在聚光硅太阳能电池焊料层的Sn3.0Ag0.5Cu/Cu互连中析出的Cu₆Sn₅晶须

Cu₆Sn₅ Whiskers Precipitated in Sn3.0Ag0.5Cu/Cu Interconnection in Concentrator Silicon Solar Cells Solder Layer.

作者信息

Zhang Liang, Liu Zhi-Quan, Yang Fan, Zhong Su-Juan

机构信息

School of Mechatronic Engineering, Jiangsu Normal University, Xuzhou 221116, China.

Institute of Metal Research, Chinese Academy of Science, Shenyang 110016, China.

出版信息

Materials (Basel). 2017 Mar 23;10(4):327. doi: 10.3390/ma10040327.

DOI:10.3390/ma10040327
PMID:28772686
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5506998/
Abstract

Cu₆Sn₅ whiskers precipitated in Sn3.0Ag0.5Cu/Cu interconnection in concentrator silicon solar cells solder layer were found and investigated after reflow soldering and during aging. Ag₃Sn fibers can be observed around Cu₆Sn₅ whiskers in the matrix microstructure, which can play an active effect on the reliability of interconnection. Different morphologies of Cu₆Sn₅ whiskers can be observed, and hexagonal rod structure is the main morphology of Cu₆Sn₅ whiskers. A hollow structure can be observed in hexagonal Cu₆Sn₅ whiskers, and a screw dislocation mechanism was used to represent the Cu₆Sn₅ growth. Based on mechanical property testing and finite element simulation, Cu₆Sn₅ whiskers were regarded as having a negative effect on the durability of Sn3.0Ag0.5Cu/Cu interconnection in concentrator silicon solar cells solder layer.

摘要

在聚光硅太阳能电池焊料层的Sn3.0Ag0.5Cu/Cu互连中发现了Cu₆Sn₅晶须,并在回流焊接后和老化过程中对其进行了研究。在基体微观结构中,可以观察到Ag₃Sn纤维围绕在Cu₆Sn₅晶须周围,这对互连的可靠性可能起到积极作用。可以观察到Cu₆Sn₅晶须的不同形态,六方棒状结构是Cu₆Sn₅晶须的主要形态。在六方Cu₆Sn₅晶须中可以观察到中空结构,并采用螺位错机制来描述Cu₆Sn₅的生长。基于力学性能测试和有限元模拟,认为Cu₆Sn₅晶须对聚光硅太阳能电池焊料层中Sn3.0Ag0.5Cu/Cu互连的耐久性有负面影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/d550162e32cc/materials-10-00327-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/56e5975d3173/materials-10-00327-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/1003712e4655/materials-10-00327-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/c508d9cc3dc7/materials-10-00327-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/a6a2a9d91434/materials-10-00327-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/5f3d399332cb/materials-10-00327-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/cd4edb37b76e/materials-10-00327-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/b124f8e692d8/materials-10-00327-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/d550162e32cc/materials-10-00327-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/56e5975d3173/materials-10-00327-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/1003712e4655/materials-10-00327-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/c508d9cc3dc7/materials-10-00327-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/a6a2a9d91434/materials-10-00327-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/5f3d399332cb/materials-10-00327-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/cd4edb37b76e/materials-10-00327-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/b124f8e692d8/materials-10-00327-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e076/5506998/d550162e32cc/materials-10-00327-g008.jpg

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