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基于聚合离子液体的吸附剂包覆磁铁矿从水溶液中去除六价铬

Chromium(VI) Removal from Aqueous Solution by Magnetite Coated by a Polymeric Ionic Liquid-Based Adsorbent.

作者信息

Ferreira Thania Alexandra, Rodriguez Jose Antonio, Paez-Hernandez María Elena, Guevara-Lara Alfredo, Barrado Enrique, Hernandez Prisciliano

机构信息

Area Academica de Quimica, Universidad Autonoma del Estado de Hidalgo, Carr. Pachuca-Tulancingo Km. 4.5, Mineral de la Reforma, Hidalgo 42184, Mexico.

Departamento de Química Analítica, Facultad de Ciencias, Universidad de Valladolid, Paseo de Belén 7, Valladolid 47011, Spain.

出版信息

Materials (Basel). 2017 May 6;10(5):502. doi: 10.3390/ma10050502.

DOI:10.3390/ma10050502
PMID:28772865
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5459042/
Abstract

An evaluation of the chromium(VI) adsorption capacity of four magnetite sorbents coated with a polymer phase containing polymethacrylic acid or polyallyl-3-methylimidazolium is presented. Factors that influence the chromium(VI) removal such as solution pH and contact time were investigated in batch experiments and in stirred tank reactor mode. Affinity and rate constants increased with the molar ratio of the imidazolium. The highest adsorption was obtained at pH 2.0 due to the contribution of electrostatic interactions.

摘要

本文对四种负载含聚甲基丙烯酸或聚烯丙基-3-甲基咪唑鎓聚合物相的磁铁矿吸附剂的六价铬吸附容量进行了评估。在间歇实验和搅拌釜反应器模式下,研究了影响六价铬去除的因素,如溶液pH值和接触时间。亲和常数和速率常数随咪唑鎓摩尔比的增加而增大。由于静电相互作用的影响,在pH值为2.0时吸附量最高。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/09d5a06fd961/materials-10-00502-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/b743a09339d1/materials-10-00502-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/713396039883/materials-10-00502-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/ae92fbdcf3ad/materials-10-00502-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/facdf3e30528/materials-10-00502-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/09d5a06fd961/materials-10-00502-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/b743a09339d1/materials-10-00502-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/713396039883/materials-10-00502-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/ae92fbdcf3ad/materials-10-00502-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/facdf3e30528/materials-10-00502-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1de1/5459042/09d5a06fd961/materials-10-00502-g005.jpg

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