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等离子体ZrN冶金与喷丸双相处理对Ti6Al4V合金微动磨损和微动疲劳行为的影响。

Effects of Plasma ZrN Metallurgy and Shot Peening Duplex Treatment on Fretting Wear and Fretting Fatigue Behavior of Ti6Al4V Alloy.

作者信息

Tang Jingang, Liu Daoxin, Zhang Xiaohua, Du Dongxing, Yu Shouming

机构信息

Institute of Corrosion and Protection, School of Aeronautics, Northwestern Polytechnical University, Xi'an 710072, China.

Institute of Machinery Manufacturing Technology, China Academy of Engineering Physics, Mianyang 621900, China.

出版信息

Materials (Basel). 2016 Mar 23;9(4):217. doi: 10.3390/ma9040217.

DOI:10.3390/ma9040217
PMID:28773345
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5502668/
Abstract

A metallurgical zirconium nitride (ZrN) layer was fabricated using glow metallurgy using nitriding with zirconiuming prior treatment of the Ti6Al4V alloy. The microstructure, composition and microhardness of the corresponding layer were studied. The influence of this treatment on fretting wear (FW) and fretting fatigue (FF) behavior of the Ti6Al4V alloy was studied. The composite layer consisted of an 8-μm-thick ZrN compound layer and a 50-μm-thick nitrogen-rich Zr-Ti solid solution layer. The surface microhardness of the composite layer is 1775 HK. A gradient in cross-sectional microhardness distribution exists in the layer. The plasma ZrN metallurgical layer improves the FW resistance of the Ti6Al4V alloy, but reduces the base FF resistance. This occurs because the improvement in surface hardness results in lowering of the toughness and increasing in the notch sensitivity. Compared with shot peening treatment, plasma ZrN metallurgy and shot peening composite treatment improves the FW resistance and enhances the FF resistance of the Ti6Al4V alloy. This is attributed to the introduction of a compressive stress field. The combination of toughness, strength, FW resistance and fatigue resistance enhance the FF resistance for titanium alloy.

摘要

采用辉光冶金法，在对Ti6Al4V合金进行锆预处理后进行渗氮处理，制备了一层冶金氮化锆（ZrN）层。研究了相应层的微观结构、成分和显微硬度。研究了这种处理对Ti6Al4V合金微动磨损（FW）和微动疲劳（FF）行为的影响。复合层由一个8μm厚的ZrN化合物层和一个50μm厚的富氮Zr-Ti固溶体层组成。复合层的表面显微硬度为1775 HK。该层存在横截面显微硬度分布梯度。等离子体ZrN冶金层提高了Ti6Al4V合金的抗微动磨损性能，但降低了基体的抗微动疲劳性能。这是因为表面硬度的提高导致韧性降低和缺口敏感性增加。与喷丸处理相比，等离子体ZrN冶金与喷丸复合处理提高了Ti6Al4V合金的抗微动磨损性能并增强了其抗微动疲劳性能。这归因于引入了压缩应力场。韧性、强度、抗微动磨损性能和抗疲劳性能的结合增强了钛合金的抗微动疲劳性能。

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