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二水合-[6,6'-亚磺酰二基双(2,2'-联吡啶)]硝酸钴(II)晶体结构中的一种压缩八面体钴(II)配合物。

A compressed octa-hedral cobalt(II) complex in the crystal structure of di-aqua-[6,6'-sulfanediylbis(2,2'-bi-pyridine)]cobalt(II) dinitrate.

作者信息

Li Guo-Ling, Sato Osamu

机构信息

Institute for Materials Chemistry and Engineering, Kyushu University, 744 Motoka, Nishi-ku, Fukuoka 819-0395, Japan.

出版信息

Acta Crystallogr E Crystallogr Commun. 2017 Jun 13;73(Pt 7):993-995. doi: 10.1107/S2056989017008428. eCollection 2017 Jul 1.

DOI:10.1107/S2056989017008428
PMID:28775868
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5499276/
Abstract

The asymmetric unit of the title salt, Co(CHNS)(HO), comprises a [Co(CHNS)(HO)] cation and two NO anions. In the complex, [Co(CHNS)(HO)] cation, the tetra-dentate 6,6'-sulfanediylbis(2,2'-bi-pyridine) ligand coordinates to the Co cation in the equatorial positions, while two water mol-ecules occupy the axial positions, forming a compressed octa-hedral CoNO coordination sphere. The NO anions are linked to the [Co(CHNS)(HO)] cations O-H⋯O hydrogen bonds, yielding a layered arrangement parallel to (001).

摘要

标题盐Co(CHNS)(HO)的不对称单元包含一个[Co(CHNS)(HO)]阳离子和两个NO阴离子。在配合物[Co(CHNS)(HO)]阳离子中，四齿的6,6'-亚磺酰基双(2,2'-联吡啶)配体在赤道位置与Co阳离子配位，而两个水分子占据轴向位置，形成一个压缩的八面体CoNO配位球。NO阴离子通过O-H⋯O氢键与[Co(CHNS)(HO)]阳离子相连，产生平行于(001)的层状排列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef20/5499276/8488b160ef51/e-73-00993-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef20/5499276/ce1c3d657e2b/e-73-00993-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef20/5499276/8488b160ef51/e-73-00993-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef20/5499276/ce1c3d657e2b/e-73-00993-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef20/5499276/8488b160ef51/e-73-00993-fig2.jpg

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