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表面等离激元纳米复合超材料吸收体综述

Review of Plasmonic Nanocomposite Metamaterial Absorber.

作者信息

Hedayati Mehdi Keshavarz, Faupel Franz, Elbahri Mady

机构信息

Nanochemistry and Nanoengineering, Faculty of Engineering, Institute for Materials Science, Christian-Albrechts-Universität zu Kiel, Kaiserstrasse 2, Kiel 24143, Germany.

Chair for Multicomponent Materials, Faculty of Engineering, Institute for Materials Science, Christian-Albrechts-Universität zu Kiel, Kaiserstrasse 2, Kiel 24143, Germany.

出版信息

Materials (Basel). 2014 Feb 14;7(2):1221-1248. doi: 10.3390/ma7021221.

Abstract

Plasmonic metamaterials are artificial materials typically composed of noble metals in which the features of photonics and electronics are linked by coupling photons to conduction electrons of metal (known as surface plasmon). These rationally designed structures have spurred interest noticeably since they demonstrate some fascinating properties which are unattainable with naturally occurring materials. Complete absorption of light is one of the recent exotic properties of plasmonic metamaterials which has broadened its application area considerably. This is realized by designing a medium whose impedance matches that of free space while being opaque. If such a medium is filled with some lossy medium, the resulting structure can absorb light totally in a sharp or broad frequency range. Although several types of metamaterials perfect absorber have been demonstrated so far, in the current paper we overview (and focus on) perfect absorbers based on nanocomposites where the total thickness is a few tens of nanometer and the absorption band is broad, tunable and insensitive to the angle of incidence. The nanocomposites consist of metal nanoparticles embedded in a dielectric matrix with a high filling factor close to the percolation threshold. The filling factor can be tailored by the vapor phase co-deposition of the metallic and dielectric components. In addition, novel wet chemical approaches are discussed which are bio-inspired or involve synthesis within levitating Leidenfrost drops, for instance. Moreover, theoretical considerations, optical properties, and potential application of perfect absorbers will be presented.

摘要

表面等离激元超材料是一类人工材料,通常由贵金属组成,其中光子学和电子学的特性通过将光子与金属的传导电子(称为表面等离激元)耦合而联系起来。这些经过合理设计的结构显著激发了人们的兴趣,因为它们展现出了一些天然材料所无法实现的迷人特性。光的完全吸收是表面等离激元超材料最近呈现的奇异特性之一,这极大地拓宽了其应用领域。这是通过设计一种阻抗与自由空间匹配但不透明的介质来实现的。如果这种介质填充一些有损介质,所得到的结构能够在一个尖锐或较宽的频率范围内完全吸收光。尽管到目前为止已经展示了几种类型的超材料完美吸收体,但在本文中,我们概述(并重点关注)基于纳米复合材料的完美吸收体,其总厚度为几十纳米,吸收带宽、可调谐且对入射角不敏感。这些纳米复合材料由嵌入介电基体中的金属纳米颗粒组成,填充因子高且接近渗流阈值。填充因子可通过金属和介电成分的气相共沉积来调整。此外还讨论了新颖的湿化学方法,例如受生物启发的方法或涉及在悬浮的莱顿弗罗斯特滴内进行合成 的方法。此外,还将介绍完美吸收体的理论考量、光学性质和潜在应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bfd6/5453083/3ab001a8a3d9/materials-07-01221f1.jpg

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