• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

对自组装施加控制：含四种组分的混合金属、混合配体配位笼的合理设计与合成

Imposing control on self-assembly: rational design and synthesis of a mixed-metal, mixed-ligand coordination cage containing four types of component.

作者信息

Metherell Alexander J, Ward Michael D

机构信息

Department of Chemistry , University of Sheffield , Sheffield S3 7HF , UK . Email:

出版信息

Chem Sci. 2016 Feb 1;7(2):910-915. doi: 10.1039/c5sc03526k. Epub 2015 Oct 14.

DOI:10.1039/c5sc03526k
PMID:28791122
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5530507/
Abstract

Retrosynthetic analysis of a [ML] coordination cage shows how it can be assembled rationally, in a stepwise manner, using a combination of kinetically inert and kinetically labile components. Combination of the components of -Ru(L), Cd(BF) and L in the necessary 4 : 12 : 12 stoichiometry afforded crystals of [RuCd(L)(L)]X (X = a mono-anion) in which the location of the two types of metal ion [Ru(ii) or Cd(ii)] at specific vertices in the metal-ion array, and the two types of bridging ligand (L and L) along specific edges, is completely controlled by the synthetic strategy. The incorporation of four different types of component at pre-determined positions in a coordination cage superstructure represents a substantial advance in imposing control on the self-assembly of complex metallosupramolecular entities.

摘要

对一种[ML]配位笼的逆合成分析表明了如何以逐步的方式，通过结合动力学惰性和动力学不稳定的组分来合理地组装它。以4∶12∶12的化学计量比将Ru(L)、Cd(BF)和L的组分相结合，得到了[RuCd(L)(L)]X（X为单阴离子）晶体，其中两种类型的金属离子[Ru(ii)或Cd(ii)]在金属离子阵列中特定顶点的位置，以及沿着特定边的两种类型的桥连配体（L和L），完全由合成策略控制。在配位笼超结构的预定位置引入四种不同类型的组分，代表了在对复杂金属超分子实体的自组装施加控制方面取得的重大进展。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/7235e474b85b/c5sc03526k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/2e186048fc36/c5sc03526k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/12ed01d8d53f/c5sc03526k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/1800b117c5a9/c5sc03526k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/d5b94227853e/c5sc03526k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/b22cf8f37897/c5sc03526k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/3cf216d0066d/c5sc03526k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/64f9c7878dbb/c5sc03526k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/2c1016ebf468/c5sc03526k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/7235e474b85b/c5sc03526k-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/2e186048fc36/c5sc03526k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/12ed01d8d53f/c5sc03526k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/1800b117c5a9/c5sc03526k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/d5b94227853e/c5sc03526k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/b22cf8f37897/c5sc03526k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/3cf216d0066d/c5sc03526k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/64f9c7878dbb/c5sc03526k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/2c1016ebf468/c5sc03526k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/622f/5530507/7235e474b85b/c5sc03526k-f9.jpg

相似文献

1
Imposing control on self-assembly: rational design and synthesis of a mixed-metal, mixed-ligand coordination cage containing four types of component.对自组装施加控制：含四种组分的混合金属、混合配体配位笼的合理设计与合成
Chem Sci. 2016 Feb 1;7(2):910-915. doi: 10.1039/c5sc03526k. Epub 2015 Oct 14.
2
Stepwise assembly of mixed-metal coordination cages containing both kinetically inert and kinetically labile metal ions: introduction of metal-centred redox and photophysical activity at specific sites.包含动力学惰性和动力学活性金属离子的混合金属配位笼的逐步组装：在特定位置引入以金属为中心的氧化还原和光物理活性。
Dalton Trans. 2015 Nov 7;44(41):17939-49. doi: 10.1039/c5dt02957k. Epub 2015 Sep 25.
3
Coordination chemistry of tetradentate N-donor ligands containing two pyrazolyl-pyridine units separated by a 1,8-naphthyl spacer: dodecanuclear and tetranuclear coordination cages and cyclic helicates.含由1,8-萘基间隔基隔开的两个吡唑基吡啶单元的四齿氮供体配体的配位化学：十二核和四核配位笼及环状螺旋配合物
Inorg Chem. 2006 May 15;45(10):3905-19. doi: 10.1021/ic060157d.
4
Stepwise synthesis of a Ru₄Cd₄ coordination cage using inert and labile subcomponents: introduction of redox activity at specific sites.使用惰性和活性亚组分逐步合成Ru₄Cd₄配位笼：在特定位置引入氧化还原活性
Chem Commun (Camb). 2014 Jun 18;50(48):6330-2. doi: 10.1039/c4cc02627f.
5
Stepwise assembly of an adamantoid Ru₄Ag₆ cage by control of metal coordination geometry at specific sites.通过控制特定位点的金属配位几何结构逐步组装金刚烷型Ru₄Ag₆笼。
Chem Commun (Camb). 2014 Sep 28;50(75):10979-82. doi: 10.1039/c4cc05421k. Epub 2014 Aug 6.
6
Fac and mer isomers of Ru(II) tris(pyrazolyl-pyridine) complexes as models for the vertices of coordination cages: structural characterisation and hydrogen-bonding characteristics.Ru(II) 三（吡唑基吡啶）配合物的 fac 和 mer 异构体作为配位笼顶点的模型：结构特征和氢键特征。
Dalton Trans. 2014 Jan 7;43(1):71-84. doi: 10.1039/c3dt52479e.
7
Structures, host-guest chemistry and mechanism of stepwise self-assembly of M4L6 tetrahedral cage complexes.M4L6 四面体型笼状配合物的分步自组装的结构、主体-客体化学和机理。
Dalton Trans. 2011 Dec 7;40(45):12132-45. doi: 10.1039/c1dt10781j. Epub 2011 Aug 10.
8
Mixed-ligand molecular paneling: dodecanuclear cuboctahedral coordination cages based on a combination of edge-bridging and face-capping ligands.混合配体分子镶嵌：基于边桥联配体和面封端配体组合的十二核立方八面体配位笼。
J Am Chem Soc. 2008 Sep 3;130(35):11641-9. doi: 10.1021/ja803847w. Epub 2008 Aug 8.
9
Structures and dynamic behavior of large polyhedral coordination cages: an unusual cage-to-cage interconversion.多面体型配位笼的结构和动态行为：一种不寻常的笼-笼互变。
J Am Chem Soc. 2011 Feb 2;133(4):858-70. doi: 10.1021/ja107403p. Epub 2010 Dec 22.
10
Cubes, squares, and books: a simple transition metal/bridging ligand combination can lead to a surprising range of structural types with the same metal/ligand proportions.立方体、正方形和书本：简单的过渡金属/桥联配体组合可以导致具有相同金属/配体比例的令人惊讶的多种结构类型。
Inorg Chem. 2009 Dec 21;48(24):11871-81. doi: 10.1021/ic901892y.

引用本文的文献

1
Triamine and Tetramine Edge-Length Matching Drives Heteroleptic Triangular and Tetragonal Prism Assembly.三胺和四胺的边长匹配驱动杂配三角和四方棱柱组装。
J Am Chem Soc. 2024 Feb 28;146(8):5215-5223. doi: 10.1021/jacs.3c11320. Epub 2024 Feb 13.
2
Synthesis and characterization of heterometallic rings templated through alkylammonium or imidazolium cations.通过烷基铵或咪唑鎓阳离子模板合成和表征杂金属环。
Dalton Trans. 2023 Jun 6;52(22):7473-7481. doi: 10.1039/d3dt00982c.
3
Templating metallocycles with a macrocycle: synthesis, structures and magnetic studies of {CrM} complexes.

本文引用的文献

1
pH-dependent binding of guests in the cavity of a polyhedral coordination cage: reversible uptake and release of drug molecules.客体在多面体配位笼腔内的pH依赖性结合：药物分子的可逆摄取与释放
Chem Sci. 2015 Jan 1;6(1):625-631. doi: 10.1039/c4sc02090a. Epub 2014 Jul 31.
2
Stepwise assembly of mixed-metal coordination cages containing both kinetically inert and kinetically labile metal ions: introduction of metal-centred redox and photophysical activity at specific sites.包含动力学惰性和动力学活性金属离子的混合金属配位笼的逐步组装：在特定位置引入以金属为中心的氧化还原和光物理活性。
Dalton Trans. 2015 Nov 7;44(41):17939-49. doi: 10.1039/c5dt02957k. Epub 2015 Sep 25.
3
大环模板化金属环：{CrM}配合物的合成、结构和磁性研究。
Dalton Trans. 2022 Dec 20;52(1):20-23. doi: 10.1039/d2dt03368b.
4
Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes.超越柏拉图：如何构建能够结合低对称、信息丰富的分子货物的金属有机多面体。
Chem Rev. 2022 Jun 8;122(11):10393-10437. doi: 10.1021/acs.chemrev.1c00763. Epub 2022 Apr 18.
5
Multi-functional, Low Symmetry Pd L Nanocage Libraries*.多功能、低对称性钯镧纳米笼库*
Chemistry. 2021 Mar 1;27(13):4454-4460. doi: 10.1002/chem.202005363. Epub 2021 Feb 1.
6
Better Together: Functional Heterobimetallic Macrocyclic and Cage-like Assemblies.协同更优：功能性异双金属大环与笼状组装体
Chemistry. 2020 Oct 21;26(59):13332-13346. doi: 10.1002/chem.202001602. Epub 2020 Sep 11.
7
Anion Recognition as a Supramolecular Switch of Cell Internalization.阴离子识别作为细胞内化的超分子开关
J Am Chem Soc. 2017 Jan 11;139(1):55-58. doi: 10.1021/jacs.6b11103. Epub 2016 Dec 21.
Supramolecular catalysis in metal-ligand cluster hosts.
金属-配体簇主体中的超分子催化作用。
Chem Rev. 2015 May 13;115(9):3012-35. doi: 10.1021/cr4001226. Epub 2015 Apr 21.
4
mer and fac isomerism in tris chelate diimine metal complexes.三螯合二亚胺金属配合物中的顺反异构现象。
Dalton Trans. 2015 Mar 14;44(10):4406-22. doi: 10.1039/c4dt03535f.
5
Controllable coordination-driven self-assembly: from discrete metallocages to infinite cage-based frameworks.可控配位驱动自组装：从离散金属笼到无限基于笼的框架。
Acc Chem Res. 2015 Feb 17;48(2):201-10. doi: 10.1021/ar5003076. Epub 2014 Dec 17.
6
Stepwise assembly of an adamantoid Ru₄Ag₆ cage by control of metal coordination geometry at specific sites.通过控制特定位点的金属配位几何结构逐步组装金刚烷型Ru₄Ag₆笼。
Chem Commun (Camb). 2014 Sep 28;50(75):10979-82. doi: 10.1039/c4cc05421k. Epub 2014 Aug 6.
7
Stepwise synthesis of a Ru₄Cd₄ coordination cage using inert and labile subcomponents: introduction of redox activity at specific sites.使用惰性和活性亚组分逐步合成Ru₄Cd₄配位笼：在特定位置引入氧化还原活性
Chem Commun (Camb). 2014 Jun 18;50(48):6330-2. doi: 10.1039/c4cc02627f.
8
Fac and mer isomers of Ru(II) tris(pyrazolyl-pyridine) complexes as models for the vertices of coordination cages: structural characterisation and hydrogen-bonding characteristics.Ru(II) 三（吡唑基吡啶）配合物的 fac 和 mer 异构体作为配位笼顶点的模型：结构特征和氢键特征。
Dalton Trans. 2014 Jan 7;43(1):71-84. doi: 10.1039/c3dt52479e.
9
Giant hollow M(n)L(2n) spherical complexes: structure, functionalisation and applications.巨型中空 M(n)L(2n) 球形配合物：结构、功能化与应用。
Chem Commun (Camb). 2013 Aug 4;49(60):6703-12. doi: 10.1039/c3cc43191f.
10
Cu12 and Cd16 coordination cages and their Cu3 and Cd3 subcomponents, and the role of inter-ligand π-stacking in stabilising cage complexes.Cu12 和 Cd16 配位笼及其 Cu3 和 Cd3 亚基，以及分子间π-堆积在稳定笼状配合物中的作用。
Dalton Trans. 2013 May 21;42(19):6756-67. doi: 10.1039/c3dt50161b.