Schotman Tom G, Xu Xiaoma, Rodewijk Nicole, van der Weerd Jaap
Netherlands Forensic Institute, Division of Chemical and Physical Traces, P.O. Box 24044, 2490AA The Hague, The Netherlands.
Forensic Sci Int. 2017 Sep;278:338-350. doi: 10.1016/j.forsciint.2017.07.026. Epub 2017 Jul 31.
Seven cases and a quality assurance test are presented. In these cases, fibres or textiles submitted for investigation were analysed by HPLC-DAD-MS to identify the dyes present. The cases presented illustrate that it is possible to identify textile dyes in fibre traces recovered for forensic analysis. The results show that a mixture of dyes is present in all textiles investigated, except one sample that was taken from a manufacturer dye shade card. It is concluded that dye analyses improves the evidential value of forensic fibre examinations, as it becomes possible to distinguish textiles that are different in dye chemistry, but have a similar colour. In addition dye analysis makes the examination more robust, as it becomes possible to attribute colour differences between samples to identical dyes (mixed in different ratios) or to chemically different dyes.
本文介绍了七个案例及一项质量保证测试。在这些案例中,提交进行调查的纤维或纺织品通过高效液相色谱-二极管阵列-质谱联用仪(HPLC-DAD-MS)进行分析,以识别其中存在的染料。所展示的案例表明,在为法医分析而回收的纤维痕迹中识别纺织染料是可行的。结果显示,除了一个取自制造商染料色卡的样品外,所有被调查的纺织品中都存在染料混合物。得出的结论是,染料分析提高了法医纤维检验的证据价值,因为可以区分染料化学性质不同但颜色相似的纺织品。此外,染料分析使检验更加可靠,因为可以将样品之间的颜色差异归因于相同的染料(以不同比例混合)或化学性质不同的染料。