Su Wei-Xiang, Wu Chun-Ying, Lee Yung-Chun
Department of Mechanical Engineering, National Cheng-Kung University, Tainan 701, Taiwan.
Sensors (Basel). 2017 Aug 13;17(8):1867. doi: 10.3390/s17081867.
This paper presents a direct contact printing method to obtain arrayed metallic nanostructures on a soft polymer substrate. It utilizes a polydimethylsiloxane (PDMS) mold replicated from silicon molds to transfer metallic nanopatterns onto a polymer substrate based on differences in interfacial bonding energy. Arrayed metallic nanodisks with a disk diameter down to 180 nm and a center-to-center pitch around 400 nm are experimentally patterned on a PET substrate. The patterned metallic nanostructures are then spin-coated with a polymer layer; which mechanically secures the patterned nanostructures and optically allows waveguide plasmon resonance being excited by incident EM waves. Both experimental works and theoretical modeling are given to illustrate the behaviors of different types of plasmon resonance. These arrayed metallic nanostructures patterned on a soft polymer substrate and their tunable optical characteristics open up many possibilities in future engineering applications.
本文提出了一种直接接触印刷方法,用于在柔软的聚合物基底上获得阵列化金属纳米结构。该方法利用从硅模具复制而来的聚二甲基硅氧烷(PDMS)模具,基于界面结合能的差异将金属纳米图案转移到聚合物基底上。实验在聚对苯二甲酸乙二酯(PET)基底上制备出了直径低至180 nm且中心间距约为400 nm的阵列化金属纳米盘。然后在图案化的金属纳米结构上旋涂一层聚合物层,这层聚合物在机械上固定了图案化的纳米结构,并在光学上使波导等离子体激元共振能够被入射电磁波激发。通过实验工作和理论建模来说明不同类型等离子体激元共振的行为。这些在柔软聚合物基底上图案化的阵列化金属纳米结构及其可调谐光学特性为未来的工程应用开辟了许多可能性。