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基于异硫茚（ITN）和3,4-亚乙基二氧噻吩（EDOT）的低带隙液晶共轭聚合物的合成

Synthesis of Isothianaphthene (ITN) and 3,4-Ethylenedioxy-Thiophene (EDOT)-Based Low-Bandgap Liquid Crystalline Conjugated Polymers.

作者信息

Wang Aohan, Kawabata Kohsuke, Goto Hiromasa

机构信息

Faculty of Pure and Applied Sciences, Division of Materials Science, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan.

出版信息

Materials (Basel). 2013 May 30;6(6):2218-2228. doi: 10.3390/ma6062218.

DOI:10.3390/ma6062218
PMID:28809269
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5458956/
Abstract

Copolymers, consisting of isothianaphthene and phenylene derivatives with liquid crystal groups, were synthesized via Migita-Kosugi-Stille polycondensation reaction. IR absorption, UV-vis optical absorption, and PL spectroscopy measurements were carried out. Thermotropic liquid crystallinity of the polymers with bandgap of ~2.5 eV was confirmed.

摘要

通过Migita-Kosugi-Stille缩聚反应合成了由异噻萘并和带有液晶基团的亚苯基衍生物组成的共聚物。进行了红外吸收、紫外-可见光学吸收和光致发光光谱测量。证实了带隙约为2.5 eV的聚合物具有热致液晶性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/1fd26df432e4/materials-06-02218-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/f3433c7b7344/materials-06-02218-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/26824fbf6bce/materials-06-02218-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/4e5751be7150/materials-06-02218-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/d4ace9cca1b6/materials-06-02218-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/00df87329e94/materials-06-02218-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/70c4f976c211/materials-06-02218-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/9d216bcc6955/materials-06-02218-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/ca985ea8c41c/materials-06-02218-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/00135a3e3a2d/materials-06-02218-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/7de50dfaa43e/materials-06-02218-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/f740e0824016/materials-06-02218-g006.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/1fd26df432e4/materials-06-02218-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/f3433c7b7344/materials-06-02218-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/26824fbf6bce/materials-06-02218-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/4e5751be7150/materials-06-02218-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/d4ace9cca1b6/materials-06-02218-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/00df87329e94/materials-06-02218-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/70c4f976c211/materials-06-02218-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/9d216bcc6955/materials-06-02218-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/ca985ea8c41c/materials-06-02218-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/00135a3e3a2d/materials-06-02218-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/7de50dfaa43e/materials-06-02218-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/f740e0824016/materials-06-02218-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/4cd980692546/materials-06-02218-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e61c/5458956/1fd26df432e4/materials-06-02218-g008.jpg

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