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胆甾相液晶乳液的相转变动力学。

Switching dynamics in cholesteric liquid crystal emulsions.

机构信息

Dipartimento di Fisica and Sezione INFN, Università di Bari, Via Amendola 173, 70126 Bari, Italy.

SUPA, School of Physics and Astronomy, University of Edinburgh, Edinburgh EH9 3JZ, United Kingdom.

出版信息

J Chem Phys. 2017 Aug 14;147(6):064903. doi: 10.1063/1.4997637.

Abstract

In this work we numerically study the switching dynamics of a 2D cholesteric emulsion droplet immersed in an isotropic fluid under an electric field, which is either uniform or rotating with constant speed. The overall dynamics depend strongly on the magnitude and on the direction (with respect to the cholesteric axis) of the applied field, on the anchoring of the director at the droplet surface and on the elasticity. If the surface anchoring is homeotropic and a uniform field is parallel to the cholesteric axis, the director undergoes deep elastic deformations and the droplet typically gets stuck into metastable states which are rich in topological defects. When the surface anchoring is tangential, the effects due to the electric field are overall less dramatic, as a small number of topological defects form at equilibrium. The application of the field perpendicular to the cholesteric axis usually has negligible effects on the defect dynamics. The presence of a rotating electric field of varying frequency fosters the rotation of the defects and of the droplet as well, typically at a lower speed than that of the field, due to the inertia of the liquid crystal. If the surface anchoring is homeotropic, a periodic motion is found. Our results represent a first step to understand the dynamical response of a cholesteric droplet under an electric field and its possible application in designing novel liquid crystal-based devices.

摘要

在这项工作中,我们通过数值模拟研究了浸入各向同性流体中的二维胆甾相乳液滴在电场作用下的动力学行为,该电场可以是均匀的或具有恒定速度的旋转场。整体动力学行为强烈依赖于所施加电场的大小和方向(相对于胆甾相轴)、指向矢在液滴表面的锚定以及弹性。如果表面锚定是垂直的且均匀场与胆甾相轴平行,则指向矢会发生深度弹性变形,液滴通常会陷入富含拓扑缺陷的亚稳状态。当表面锚定是切向的时,电场的影响总体上不那么显著,因为在平衡时只会形成少量拓扑缺陷。垂直于胆甾相轴的电场的应用通常对缺陷动力学的影响可以忽略不计。具有变化频率的旋转电场的存在促进了缺陷和液滴的旋转,通常由于液晶的惯性,其速度比场的速度要低。如果表面锚定是垂直的,则会发现周期性运动。我们的结果代表了理解电场下胆甾相液滴动力学响应及其在设计新型基于液晶的器件中的可能应用的第一步。

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