由氨基酸衍生的萘二亚胺组装体自组装成具有湿度敏感n型半导体特性的纳米纤维超结构。
Self-organization of amino-acid-derived NDI assemblies into a nanofibrillar superstructure with humidity sensitive n-type semiconducting properties.
作者信息
Squillaci Marco A, Markiewicz Grzegorz, Walczak Anna, Ciesielski Artur, Stefankiewicz Artur R, Samorì Paolo
机构信息
University of Strasbourg, CNRS, ISIS UMR 7006, 8 allée Gaspard Monge, F-67000 Strasbourg, France.
出版信息
Chem Commun (Camb). 2017 Aug 29;53(70):9713-9716. doi: 10.1039/c7cc04822j.
PMID:28812063
Abstract
The hierarchical self-assembly of l-tyrosine substituted naphthalenediimide has been explored in solution by NMR spectroscopy and in the solid-state by atomic force microscopy. Spontaneous non-covalent polymerisation led to the formation of a three-dimensional fibre-like supramolecular polymer with n-type semiconducting properties.
摘要
通过核磁共振光谱在溶液中以及通过原子力显微镜在固态下研究了L-酪氨酸取代的萘二亚胺的分级自组装。自发的非共价聚合导致形成具有n型半导体性质的三维纤维状超分子聚合物。
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