萘酚合成：通过铑（III）催化的C-H活化实现硝酮与炔烃的环化反应。
Naphthol synthesis: annulation of nitrones with alkynes via rhodium(iii)-catalyzed C-H activation.
作者信息
Wang Qiang, Xu Youwei, Yang Xifa, Li Yunyun, Li Xingwei
机构信息
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China.
出版信息
Chem Commun (Camb). 2017 Aug 24;53(69):9640-9643. doi: 10.1039/c7cc05000c.
PMID:28812084
Abstract
An efficient and redox-neutral naphthol synthesis has been realized via rhodium(iii) catalyzed C-H activation of α-carbonyl nitrones and annulation with alkynes, where the nitrone group functioned as a traceless directing group.
摘要
通过铑（III）催化的α-羰基硝酮的C-H活化以及与炔烃的环化反应，实现了一种高效且氧化还原中性的萘酚合成方法，其中硝酮基团作为无痕导向基团。
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