Cocatalyzing Pt/PtO Phase-Junction Nanodots on Hierarchically Porous TiO for Highly Enhanced Photocatalytic Hydrogen Production.

Phase-junctions between a cocatalyst and its semiconductor host are quite effective to enhance the photocatalytic activity and are widely studied, while reports on the phase-juncted cocatalyst are still rare. In this work, we report the deposition of the Pt/PtO phase-juncted nanodots as cocatalyst via NaOH modification of an interconnected meso-macroporous TiO network with high surface area and inner-particle mesopores to enhance the performance of photocatalytic H production. Our results show that NaOH modification can largely influence Pt/PtO phase-juncted nanodot formation and dispersity. Compared to the TiO nanoparticles, the hierarchically meso-macroporous TiO network containing 0.18 wt % Pt/PtO phase-juncted cocatalyst demonstrates a highest photocatalytic H rate of 13 mmol g h under simulated solar light, and possesses a stable cycling activity without obvious decrease after five cycles. Such high H production performance can be attributed to both the phase-juncted Pt/PtO providing more active sites while PtO suppresses the undesirable hydrogen back reaction, and the special hierarchically porous TiO network with inner-particle mesopores presenting short diffusion path lengths for photogenerated electrons and enhanced light harvesting efficiency. This work suggests that Pt/PtO phase-juncted cocatalyst on hierarchically porous TiO nanostructures is a promising strategy for advanced photocatalytic H production.