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有机硒催化的氧化 C=C 键断裂：用过氧化氢将烯烃相对绿色地氧化为羰基化合物。

Organoselenium-Catalyzed Oxidative C═C Bond Cleavage: A Relatively Green Oxidation of Alkenes into Carbonyl Compounds with Hydrogen Peroxide.

机构信息

School of Chemistry and Chemical Engineering, Yangzhou University , Yangzhou, Jiangsu 225002, China.

出版信息

J Org Chem. 2017 Sep 15;82(18):9342-9349. doi: 10.1021/acs.joc.7b01245. Epub 2017 Aug 30.

DOI:10.1021/acs.joc.7b01245
PMID:28813150
Abstract

A relatively green oxidative C═C bond cleavage of alkenes was achieved by organoselenium-catalyzed alkene oxidation reaction in ethanol with hydrogen peroxide, affording carbonyl compounds under relatively mild conditions. It is a new reaction style for the organoselenium-catalyzed oxidation of alkenes and largely contributes to the growing field of organoselenium catalysis.

摘要

通过醇中有机硒催化的烯烃氧化反应，用过氧化氢实现了相对绿色的 C═C 键的氧化断裂，在相对温和的条件下得到了羰基化合物。这是一种新的有机硒催化烯烃氧化反应的反应类型，为有机硒催化领域的发展做出了重要贡献。

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